QUANTUM CHEMICAL STUDY OF RAMAN SPECTROSCOPY OF SUBSTITUTED BENZENE DERIVATIVES ADSORBED ON METAL SURFACES

机译：金属表面吸附的取代苯衍生物拉曼光谱法的量子化学研究

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Surface-enhanced Raman spectroscopy (SERS) can be applied to obtain the information of molecules at the noble metal surfaces. But there are a number of difficulties to clearly correlate Raman spectra with microscopic molecular structures on metal surfaces. The main reason is that it is difficult to characterize unambiguously the metal surface structures and the influence of the binding interaction on SERS signals of the probe molecules. According to the surface selection rule of SERS, the electromagnetic enhancement will not change relative Raman intensities of vibrational modes with the same irreducible representation. Therefore, the change of the relative Raman intensities of the total symmetric modes may only originate from the chemical enhancement.

机译：表面增强的拉曼光谱（SERS）可以应用于获得贵金属表面处的分子信息。但是，在金属表面上用微观分子结构明显地相关的拉曼光谱存在许多困难。主要原因是难以表征明确的金属表面结构和对探针分子SERS信号的影响。根据SERS的表面选择规则，电磁增强不会改变具有相同不可缩短的表示的振动模式的相对拉曼强度。因此，总对称模式的相对拉曼强度的变化可能仅源自化学增强。

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《International Symposium on Molecular Spectroscopy》|2011年||共1页
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DE-YIN WU; ZHONG-QUN TIAN;
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4. QUANTUM CHEMICAL STUDY OF RAMAN SPECTROSCOPY OF SUBSTITUTED BENZENE DERIVATIVES ADSORBED ON METAL SURFACES [C] . DE-YIN WU, ZHONG-QUN TIAN International Symposium on Molecular Spectroscopy . 2011

机译：金属表面吸附的取代苯衍生物拉曼光谱法的量子化学研究
5. Waveguide Surface Coherent anti-Stokes Raman Scattering Spectroscopy and optical second harmonic generation spectroscopy of molecules adsorbed on metal oxide surfaces. [D] . Wijekoon, Wijekoon Mudiyanselage Kapila Piyasena. 1988

机译：波导表面相干抗斯托克斯拉曼散射光谱和光学二次谐波光谱，用于吸附在金属氧化物表面的分子。
6. Molecular switches from benzene derivatives adsorbed on metal surfaces [O] . Wei Liu, Sergey N. Filimonov, Javier Carrasco, -1

机译：吸附在金属表面的苯衍生物的分子开关
7. Waveguide Surface Coherent anti-Stokes Raman Scattering Spectroscopy and optical second harmonic generation spectroscopy of molecules adsorbed on metal oxide surfaces. [O] . Wijekoon Wijekoon Mudiyanselage Kapila Piyasena 1988

机译：波导表面相干抗斯托克斯拉曼散射光谱和光学二次谐波光谱，用于吸附在金属氧化物表面的分子。
8. Surface-Enhanced Raman Spectroscopy as a Probe or Adsorbate-Surface Bonding: Benzene and Monosubstituted Benzenes Adsorbed at Gold Electrodes [R] . Gao, P., Weaver, M. J. 1985

机译：表面增强拉曼光谱作为探针或吸附物 - 表面键合：苯和单取代苯吸附在金电极上

QUANTUM CHEMICAL STUDY OF RAMAN SPECTROSCOPY OF SUBSTITUTED BENZENE DERIVATIVES ADSORBED ON METAL SURFACES

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