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Technical and Economic Feasibility of Direct Methane Conversion for Hydrocarbon Production:Process Design and Techno-economic Analysis

机译:碳氢化合物生产直接甲烷转化技术和经济可行性:工艺设计与技术经济分析

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In this study,we have developed a modelling and evaluation framework of a direct conversion of methane(CH4)to value-added chemicals including light hydrocarbons,FT fuels,and aromatics.As novel catalysts for a direct CH4 conversion are targeted to adapt to industrial applications,it is important to access the technological and economic feasibility.Various techniques in process systems engineering play a crucial role here in the application of the current or extended methodologies to support R&D targets and planning:identification of major cost-and energy-drivers,preliminary process scheme and debottleneck strategies.In this framework,we developed a conceptual conversion process,which consists of a reaction section of directly converting CH4 into hydrocarbons,and a separation section of sequentially integrated technologies for recycles of CH4,purifying ethylene,other C2+ hydrocarbon,and aromatics production.Then,the technical and economic feasibility of the process was evaluated,included a sensitivity analysis for identifying the bottleneck factors.Outstandingly,the direct methane conversion process achieves high energy efficiency(58.9 %),consumed a large amount of utility but still overcomes the intensive-energy penalty as in other petrochemical processes that are primarily due to the contribution of hydrogen as a byproduct.The ethylene as one of main products was produced at 0.97 $/kg that can be reduced and competitive to the market in promised scenarios.Otherwise,the study provides the perspective on improving catalyst performance(e.g.higher yield of ethylene),which is critical to achieve high technical performance and economic benefits.
机译:在这项研究中,我们已经开发了一种甲烷(CH4)直接转化为增值化学品的建模和评估框架,包括轻质烃,FT燃料和芳烃。用于直接CH4转化率的新型催化剂旨在适应工业应用程序,重要的是进入技术和经济可行性。过程系统工程中的一定技术在这里在应用当前或扩展方法中发挥关键作用,以支持研发目标和规划:识别主要的成本和能源司机,初步过程计划和脱丝瓜策略。在此框架中,我们开发了一种概念转换过程,该过程由直接将CH4转化为烃的反应部分,以及依次综合技术的分离部分,用于回收CH4,纯化乙烯,其他C2 +烃。和芳烃生产。该过程的技术和经济可行性包括在内,包括识别瓶颈因素的灵敏度分析。直接甲烷转换过程实现高能量效率(58.9%),消耗大量实用,但仍克服了在其他主要是由于主要因素的碳化过程中氢作为副产品的贡献。作为主要产品之一的乙烯在0.97 $ / kg中生产,可以减少和竞争市场,在承诺的情景中。否则,该研究提供了提高催化剂性能的视角(效率乙烯),这对于实现高技术性能和经济效益至关重要。

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