COUPLING OF CATALYTIC PARTIAL OXIDATION AND STEAM REFORMING OF METHANE TO SYNGAS

机译：催化局部氧化与甲烷蒸汽重整的偶联与合成气

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Methane-to-syngas (i.e.CO and H,) conversion reactions involving exothermic oxidative conversion of methane and endothemic steam reforming of methane have been carried simultaneously NiO-CaO (Hi/Ca = 3.0) catalyst at different temperatures (700- 850°C), CH4/O2 (1.8 - 6.0) and CH4/H,0 (1.6- 10.0) ratios and space velocities (16 x 103 - 1090 x 10 h- ).By the coupling of the exotheriic and endothermic reactions, it is possible to make, the CHOCSR (coupled methane oxidative conversion and steam reforming) process mildly endothermic, near thenoneutral or mildly exothermic by manipulating the process conditions (viz. temperature and feed ratios) and also to operate the process in a most energy efficient and safe manner, with requirenent of little or no external energy. Dnder the present energy crisis, the conversion of methane to syngas (with H,/CO ratio close to 2.0 which is desirable for methanol and Fischer-Tropsch synthesis) with high conversion, selectivity and productivity in a most energy efficient and safe Manner with requirement of little or no external energy is of great practical importance for the effective utilization of natural gas by its conversion to value added and/or easily transportable products via syngas routes.

机译：甲烷至合成气（IECO和H，）涉及放热氧化转化的甲烷和甲烷内蒸汽重整的转化反应已经同时在不同温度下的NiO-CaO（HI / Ca = 3.0）催化剂（700-850℃ ），CH4 / O2（1.8 - 6.0）和CH4 / H，0（1.6-10.0）比率和空间速度（16 x 103-1090 x 10 h-）。该耦合的放热和吸热反应，是可能的为了使Chocsr（偶联甲烷氧化转化率和蒸汽重整）通过操纵工艺条件（温度和饲料比率），方法温和地吸热，接近于其Ooneutral或轻微放热），并以最能效率和安全的方式操作该过程，要求很少或没有外部能量。达到目前的能量危机，将甲烷转化为合成气（具有H，/ Co比接近2.0，这对于甲醇和费城 - 滴水合成而言，具有高的转化，选择性和生产率，最能效率和安全的方式要求对于通过Syngas途径的转换，几乎没有外部能量对天然气的有效利用具有很大的实际重要性，可通过转换为增值和/或易于运输产品。

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《American Chemical Society Symposium on Methane and Alkane Conversion Chemistry》|1995年||共9页
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V.R.Choudhary; A.M.Rajput; B.Prabhakar;
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1. CO_2 reforming of methane combined with steam reforming or partial oxidation of methane to syngas over NdCoO_3 perovskite-type mixed metal-oxide catalyst [J] . Vasant R. Choudhary, Kartick C. Mondal Applied Energy . 2006,第9期

机译：NdCoO_3钙钛矿型混合金属氧化物催化剂上甲烷的CO_2重整结合蒸汽重整或甲烷部分氧化为合成气
2. Partial oxidation of methane over Ni-0/La2O3 bifunctional catalyst III. Steady state activity of methane total oxidation, dry reforming, steam reforming and partial oxidation. Sequences of elementary steps [J] . Nguyen Tri Huu, Lamacz Agata, Krzton Andrzej, Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications . 2016,第Null期

机译：Ni-0 / La2O3双功能催化剂上甲烷的部分氧化III。甲烷的全氧化，干重整，蒸汽重整和部分氧化的稳态活动。基本步骤的顺序
3. Partial oxidation of methane to syngas with or without simultaneous steam or CO2 reforming over a high-temperature stable-NiCoMgCeOx supported on zirconia-hafnia catalyst [J] . Choudhary VR, Mondal KC, Choudhary TV Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2006,第0期

机译：在氧化锆-氧化f催化剂上负载的高温稳定NiCoMgCeOx上，在有或没有同时进行蒸汽或CO2重整的情况下，甲烷部分氧化为合成气
4. COUPLING OF CATALYTIC PARTIAL OXIDATION AND STEAM REFORMING OF METHANE TO SYNGAS [C] . V.R.Choudhary, A.M.Rajput, B.Prabhakar American Chemical Society Symposium on Methane and Alkane Conversion Chemistry . 1995

机译：催化局部氧化与甲烷蒸汽重整的偶联与合成气
5. Direct reduction of sulfur dioxide to elemental sulfur by methane and partial oxidation of methane to syngas on ceria-based catalysts. [D] . Zhu, Tianli. 2000

机译：通过二氧化硫将甲烷直接还原为元素硫，并在基于二氧化铈的催化剂上将甲烷部分氧化为合成气。
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8. Gas Phase Coupling of Methyl Radicals During the Catalytic Partial Oxidation of Methane [R] . Campbell, K. D. , Morales, E. , Lunsford, J. H. 1987

机译：甲烷自催化部分氧化过程中甲基自由基的气相耦合

COUPLING OF CATALYTIC PARTIAL OXIDATION AND STEAM REFORMING OF METHANE TO SYNGAS

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