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Spectroscopic Detection and Kinetic Analysis of Short-Lived Aromatic Cation Radical Using an Electron Transfer Stopped-Flow Method

机译：电子传递停止流动法的光谱检测和短缘芳香阳离子自由基的动力学分析

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In the electrochemical oxidation of aromatic molecules in aprotic solvents,the cation radicals are formed as a result of one-electron transfer.If such cation radicals are short-lived,the spectroscopic detection should be very difficult due to the consecutive reactions.In addition,the heterogeneous natures of the electrode reaction would hinder the observation of pure absorption spectra of the cation radicals.

机译：在非质子溶剂中的芳族分子的电化学氧化中，阳离子自由基形成为单电子转移。如果这种阳离子自由基短寿命，则由于连续反应，光谱检测应该非常困难。另外，电极反应的异质性质将阻碍阳离子自由基的纯吸收光谱的观察。

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《The Meeting of the Electrochemical Society》|2001年||共1页
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Munetaka Oyama;
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中图分类化学工业;
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专利

1. Spectroscopic detection and kinetic analysis of short-lived aromatic amine cation radicals using an electron transfer stopped-flow method [J] . Munetaka Oyama Toshihiro Higuchi and Satoshi Okazaki Journal of the Chemical Society, Perkin Transactions 2 . 2001,第8期

机译：电子转移停止流法对短寿命芳香胺阳离子自由基的光谱检测和动力学分析
2. Spectroscopic detection and kinetic analysis of short-lived aromatic amine cation radicals using an electron transfer stopped-flow method [J] . Munetaka Oyama, Toshihiro Higuchi, Satoshi Okazaki Journal of the Chemical Society. Perkin Transactions 2 . 2001,第8期

机译：电子转移停流法对短寿命芳香胺阳离子自由基的光谱检测和动力学分析
3. Kinetic Analysis of Reactions of p-Anisidine and N-Methyl-p-anisidine Cation Radicals in Acetonitrile Using an Electron-Transfer Stopped-Flow Method [J] . Masashi Goto, Koji Otsuka, Xi Chen, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2004,第18期

机译：乙腈中对氨基苯甲酸酯和N-甲基-对氨基苯甲酸阳离子自由基的反应动力学的电子转移停止流分析
4. Spectroscopic Detection and Kinetic Analysis of Short-Lived Aromatic Cation Radical Using an Electron Transfer Stopped-Flow Method [C] . Munetaka Oyama The Meeting of the Electrochemical Society . 2001

机译：电子传递停止流动法的光谱检测和短缘芳香阳离子自由基的动力学分析
5. MECHANISTIC STUDIES OF THE S(RN)1 MECHANISM FOR AROMATIC SUBSTITUTION: 1. SPECTROSCOPY AND KINETICS OF ELECTRON CAPTURE BY AROMATIC SUBSTRATES, 2. ABSOLUTE RATE CONSTANTS FOR REACTIONS OF PHENYL RADICAL WITH NUCLEOPHILES (RADICAL ANIONS) [D] . HERR, DANIEL JOSEPH CHRISTIAN. 1984

机译：芳香取代的S（RN）1机理的机理研究：1.芳香族底物的电子捕获光谱和动力学，2.苯自由基与核素（自由基）反应的绝对速率常数。
6. A method for extracting rate constants from initial rates of stopped-flow kinetic data: application to a physiological electron-transfer reaction. [O] . H B Brooks, V L Davidson 1993

机译：从停止流动力学数据的初始速率中提取速率常数的方法：应用于生理电子转移反应。
7. Stopped-Flow Kinetic Investigations of One-Electron Transfer Reactions of Phenothiazines and Their Radical Cations in Aqueous Solution [O] . Lakshmanan Venkatasubramanian, Pichai Maruthamuthu 1989

机译：停止吩噻嗪的一电子转移反应的流动动力学研究及其在水溶液中的自由基阳离子

Spectroscopic Detection and Kinetic Analysis of Short-Lived Aromatic Cation Radical Using an Electron Transfer Stopped-Flow Method

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