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Synthesis of Ferrocene-quinone Conjugated Oligomers and Polymers and Their Protonation-induced Intramolecular Electron-transfer Reaction

机译：合成二茂铁 - 醌缀合的低聚物及聚合物及其质子化诱导的分子内电子转移反应

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Redox-conjugated organometallic oligomers and polymers have attracted much recent attention because of their unique electronic,optical and magnetic properties.On the other hand,proton-coupled electron transfer(PCET)between donor and acceptor molecules is a fundamentally important chemical reaction closely related to various energy conversion events in biological systems.We have recently reported the intramolecular PCET of 1:1-donor/acceptor compounds,2-(2-ferrocenylvinyl)hydroquinone,and 1-ferrocenylethynylanthra-quinone,1-FcAq,causing novel changes in structure and physical properties.These reactions are realized by a combination of several factors such as the PCET ability of quinones,the existence of a pi-conjugated spacer between ferrocene and quinone,and a matching

机译：氧化还原的有机金属低聚物和聚合物由于其独特的电子，光学和磁性而引起了最近的关注。另一方面，供体和受体分子之间的质子偶联电子转移（PCET）是与之密切相关的基本重要的化学反应。与之密切相关的化学反应生物系统中的各种能量转换事件。我们最近报道了1：1-供体/受体化合物，2-（2-二铁烷基）氢醌和1-二铁烯基乙炔蒽醌 - 醌，1-FCAQ的分子内PCET，导致结构的新改变和物理性质。这些反应是通过诸如Quinones的PCET能力之类的若干因素的组合来实现，在铁茂和醌之间存在PI缀合的间隔物，以及匹配

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《PMSE Symposia》|2002年||共1页
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Hiroshi Nishihara; Masaki Murata; Kohei Kojima;
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中图分类高分子化合物工业（高聚物工业）;
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1. Thioacetyl-Terminated Ferrocene-Anthraquinone Conjugates: Synthesis, Photo- and Electrochemical Properties Triggered by Protonation-Induced Intramolecular Electron Transfer [J] . Molecules . 2010,第1期

机译：硫乙酰基封端的二茂铁-蒽醌共轭物：质子化诱导的分子内电子转移引发的合成，光化学性质
2. New conjugated polymers with donor-acceptor architectures: Synthesis and photophysics of carbazole-quinoline and phenothiazine-quinoline copolymers and oligomers exhibiting large intramolecular charge transfer [J] . Samson A. Jenekhe, Liangde Lu, Maksudul M. Alam Macromolecules . 2001,第21期

机译：具有供体-受体结构的新型共轭聚合物：咔唑-喹啉和吩噻嗪-喹啉共聚物和低聚物的合成和光物理表现出大的分子内电荷转移
3. Enhanced triplet formation by twisted intramolecular charge-transfer excited states in conjugated oligomers and polymers [J] . King SM, Matheson R, Dias FB, The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2008,第27期

机译：共轭低聚物和聚合物中分子内电荷转移的扭曲激发态增强了三重态的形成
4. Synthesis of Ferrocene-quinone Conjugated Oligomers and Polymers and Their Protonation-induced Intramolecular Electron-transfer Reaction [C] . Hiroshi Nishihara, Masaki Murata, Kohei Kojima PMSE Symposia . 2002

机译：合成二茂铁 - 醌缀合的低聚物及聚合物及其质子化诱导的分子内电子转移反应
5. THE MECHANISM OF LEWIS ACID CATALYZED ENE REACTIONS. LEWIS ACID CATALYZED INTER- AND INTRAMOLECULAR (2+2) CYCLOADDITIONS OF CONJUGATED ALLENIC ESTERS TO ALKENES. THE REGIOCHEMISTRY OF TRIETHYLAMINE DEPROTONATION OF ALPHA, BETA-UNSATURATED ACID CHLORIDES TO FORM VINYLKETENES. ATTEMPTED SYNTHESIS OF ALPHA-BOURBONENE. [D] . RON, EYAL. 1987

机译：路易斯酸催化的烯反应的机理。路易斯酸将共轭的烯丙基酯间和分子内（2 + 2）的循环负载成烯烃。乙酰胺，β-不饱和酸氯化物形成乙烯基酮的三乙胺质子化反应的区域化学。尝试合成Alpha-Bourbonene。
6. Thioacetyl-Terminated Ferrocene-Anthraquinone Conjugates: Synthesis Photo- and Electrochemical Properties Triggered by Protonation-Induced Intramolecular Electron Transfer [O] . Wen-Wei Zhang, Mio Kondo, Takako Fujita, 2010

机译：硫乙酰基封端的二茂铁-蒽醌共轭物：质子化诱导的分子内电子转移引发的合成光化学性质
7. Thioacetyl-Terminated Ferrocene-Anthraquinone Conjugates: Synthesis, Photo- and Electrochemical Properties Triggered by Protonation-Induced Intramolecular Electron Transfer [O] . Masaki Murata, Hiroshi Nishihara, Kosuke Namiki, 2010

机译：硫乙酰基封端的二茂铁-蒽醌共轭物：质子化诱导的分子内电子转移引发的合成，光化学性质
8. Synthesis of Conjugated Polymers via Polymer Elimination Reactions [R] . Jenekhe, S. A. 1987

机译：通过聚合物消除反应合成共轭聚合物

Synthesis of Ferrocene-quinone Conjugated Oligomers and Polymers and Their Protonation-induced Intramolecular Electron-transfer Reaction

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