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Asymmetric reduction of a-hydroxy aromatic ketones to chiral aryl vicinal diols using carrot enzymatic system

机译：使用红萝卜酶系统对手性芳基邻苯二甲酸甲酮的不对称还原

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摘要

Asymmetric reduction of a-hydroxy aromatic ketones was carried out by using carrot enzymatic system and the corresponding chiral vicinal diols with special functional group were received, The optimal reaction conditions were- gained after the investigation of various influencing factors. Chiral aryl vicinal diols were obtained with good yield and excellent enantiomeric excess under the appropriate conditions. Meanwhile, the steric factors and electronic effects of the substituents at the aromatic ring were shown to have an interesting effect on the yield and enahtioselectivity.

机译：通过使用胡萝卜酶系统进行α-羟基芳族酮的不对称还原，并接受了具有特殊官能团的相应手性静脉二醇，在调查各种影响因素后获得最佳反应条件。在适当的条件下，在合适的产率和优异的对映体过量获得手性芳基邻苯二甲酸甲基二醇。同时，显示芳环中取代基的空间因子和电子效应对产率和嗅觉切除具有有趣的影响。

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来源
《AIChE Annual Meeting》|2011年||共7页
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作者
Xiang Liu; Yi Wang; Jian He Xu;
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原文格式 PDF
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中图分类 TS2-532;
关键词
asymmetric reduction; chiral vicinal diol; aromatic ketone; carrot cell;

机译：不对称减少;手性静脉;芳香酮;胡萝卜细胞;

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1. Asymmetric reduction of α-hydroxy aromatic ketones to chiral aryl vicinal diols using carrot enzymes system [J] . Xiang Liu, Yi Wang, Hai Yan Gao, 中国化学快报（英文版） . 2012,第006期

机译：使用胡萝卜酶系统将α-羟基芳族酮不对称还原为手性芳基邻二醇
2. Asymmetric reduction of α-hydroxy aromatic ketones to chiral aryl vicinal diols using carrot enzymes system [J] . Xiang Liu, Yi Wang, Hai Yan Gao, 中国化学快报：英文版 . 2012,第006期

机译：使用胡萝卜酶系统将α-羟基芳族酮不对称还原为手性芳基邻二醇
3. C 2-symmetric η 6- p-cymene-Ru(II)-phosphinite complexes: Synthesis and catalytic activity in asymmetric reduction of aromatic, methyl alkyl and alkyl/aryl ketones]]> [J] . Duygu Elma Karaka?, Murat Aydemir, Feyyaz Durap, Inorganica Chimica Acta . 2018,第期

机译：<！[cdata [chiral c 2 -symmetricη 6 < / ce：sup> - p -cymene-ru（ii） - 膦酸盐复合物：芳族，甲基烷基和烷基/芳基/芳基/芳基/芳基/芳基/芳基/芳基/芳基的合成和催化活性]]]>
4. Asymmetric reduction of a-hydroxy aromatic ketones to chiral aryl vicinal diols using carrot enzymatic system [C] . Xiang Liu, Yi Wang, Jian He Xu AIChE Annual Meeting . 2011

机译：使用红萝卜酶系统对手性芳基邻苯二甲酸甲酮的不对称还原
5. Ruthenium(II)-catalyzed asymmetric transfer hydrogenation of aromatic ketones using new ferrocene-based amino-phosphine ligands featuring planar chirality [D] . Vue, Bao 2008

机译：使用具有平面手性的新型二茂铁基氨基膦配体，钌（II）催化芳族酮的不对称转移氢化
6. Catalytic Asymmetric Mannich Reactions with Fluorinated Aromatic Ketones: Efficient Access to Chiral β-Fluoroamines [O] . Prof. Dr. Barry M. Trost, Dr. Tanguy Saget, Andreas Lerchen, -1

机译：氟化芳香酮的催化不对称曼尼希反应：有效获得手性β-氟胺
7. Asymmetric reduction and Meerwein-Ponndorf-Verley reaction of prochiral aromatic ketones in the presence of optically pure 1-aryl-2,2-dimethylpropane-1,3-diols [O] . Hu Xianming, Kellogg Richard M. 1996

机译：在光学纯的1-芳基-2,2-二甲基丙烷-1,3-二醇存在下前手性芳族酮的不对称还原和Meerwein-Ponndorf-Verley反应
8. Addition Compounds of Alkali Metal Hydrides. 32. A Comparison Study of Chiral Trialkylborohydrides and Chiral Dialkylmonoalkoxyborohydrides for the Asymmetric Reduction of Prochiral Ketones: The Effect of Comparable Chiral Alkyl a [R] . Brown, H. C., Park, W. S., Cho, B. T. 1987

机译：碱金属氢化物的加成化合物。 32.手性三烷基硼氢化物和手性二烷基单烷氧基硼氢化物对前手性酮不对称还原的比较研究：可比较的手性烷基a的影响

Asymmetric reduction of a-hydroxy aromatic ketones to chiral aryl vicinal diols using carrot enzymatic system

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