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Study of chlordecone and hexachlorocyclohexane adsorption on chemically modifled activated carbons prepared from sugarcane bagasse

机译:甘蔗渣中制备化学改性活性炭的氯芳酮和六氯环己烷吸附研究

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Large amount of sugarcane residues results from the industrial production of sugar in Guadeloupe (French West Indies). These residues, called bagasse, can be used for the production of activated carbons (ACs) with a high specific area [1]. The adsorption of two organochlorine pesticides, chlordecone (CLD) and p-hexachlorocyclohexane (P-HCH), onto bagasse activated carbons was studied previously [2]. Among the samples tested two ACs called, Bag-P1.5 and Bag-H2O, were the most effective samples to adsorb CLD and P-HCH. Bag-PL5 was prepared by chemical activation with H3PO4 whereas Bag-H2O prepared by physical activation with H2O. Adsorption of CLD on ACs surface would be probably due to hydrophobic interactions and would increase with the amount of graphitic and carbonyl groups [2]. On the other hand adsorption of P-HCH increased with the amount of carboxylic groups which can create hydrogen bond with the chlorine atoms.
机译:大量的甘蔗残留是由瓜德罗普(法国西印度群岛)的糖的工业生产。这些残留物称为甘蔗渣,可用于生产具有高特异性区域的活性炭(ACS)[1]。研究先前研究了两个有机氯农药,氯芳基(CLD)和对六氯环己烷(P-HCH)的吸附在甘蔗络活性碳中[2]。在样品中,测试了两个ACS,袋-P1.5和BAG-H2O,是吸附CLD和P-HCH的最有效的样品。通过用H3PO4的化学活化制备袋PL5,而通过用H 2 O物理活化制备的袋-H2O。 CLD对ACS表面的吸附可能是由于疏水相互作用,并且会随着石墨和羰基的量而增加[2]。另一方面,P-HCH的吸附随着羧基的量增加,其可以与氯原子产生氢键。

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