Synthesis and Photophysical Properties of Red-emitting Iridium (III) Complex Bearing Benzothiazole

机译：红发射铱（III）复合物轴承苯并噻唑的合成和光学性质

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New red phosphorescent material, (E)-2-(2-(thiophen-2-yl) vinyl)benzothiazole(2THSBT) iridium(III) acetylacetone(acac) complex [(2THSBT)_(2Ir(acac))] is synthesized from 2-methyl benzothiazole, thiophene-2-carbaldehyde and iridium trichloride anhydrate. The complex is characterized by MS and ~1H-NMR. (2THSBT)_(2Ir(acac)) gives a photoluminescence at 687nm, phosphorescent quantum yield: Φ_((2THSBT)2Ir(acac))=0.2 and E_(HOMO) = -4.8 eV, E_(LUMO) = -2.6eV, respectively. The complex may be a promising electrophosphorescent material.

机译：新的红磷光荧光材料，（E）-2-（2-（噻吩-2-基）乙烯基）苯并噻唑（2THSBT）铱（III）乙酰丙酮（ACAC）复合物[（第2次）_（2杆（ACAC））]是合成的来自2-甲基苯并噻唑，噻吩-2-碳甲醛和三氯化铱水合物。该复合物的特征在于MS和〜1H-NMR。（2THSBT）_（2IR（ACAC））在687nm处给出光致发光，磷光量子产量：φ_（（2thsbt）2 r（acac））= 0.2和e_（homo）= -4.8ev，e_（lumo）= -2.6ev ，分别。该复合物可以是有希望的电磷逸细材料。

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来源
《International Conference on Chemical, Material and Metallurgical Engineering》|2012年||共4页
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作者
XIAO Guoyong; LI Xiao; CHI Haijun; LU Yunhua; HU Zhizhi; YU Jianglong;
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中图分类 TB3-532;
关键词
Organometallic iridium complex; Phosphorescent material; Benzothiazole;

机译：有机金属铱络合物;磷光材料;苯并噻唑;

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Synthesis and Photophysical Properties of Red-emitting Iridium (III) Complex Bearing Benzothiazole

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