Synthesis and Luminescent Properties of a Novel Nanoscale Eu(III)-Carboxylate Coordination Polymer

机译：新型纳米级EU（III） - 羧酸盐配位聚合物的合成和发光性能

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To prepare nanoscale coordination polymers (NCPs) which can exhibit intense luminescence have attract an increasing interest. In this paper, we present the synthesis of a novel example of discus-like luminescent nanoscale Eu(III)-carboxylate coordination polymers. The organic ligand is a derivative of terephthalate(Na_2L) with a big side group. The Eu(III)-L NCPs was synthesized through microemulsion method, and the morphology can alter along with the changing of metal: ligand ratios. XRD results reveal that the self-assembled disk-like NCPs exhibit long-range ordered structures. The luminescent measurements showed that the resultant NCPs not only exhibits typical fluorescence of Eu(III), but also can maintain the inherent fluorescence of the ligands.

机译：为了制备可以表现出强烈发光的纳米级配位聚合物（NCP）吸引了越来越感兴趣。在本文中，我们介绍了一种微型亮型纳米级EU（III）的新型实例的合成 - 羧酸盐配位聚合物。有机配体是具有大侧基的对苯二甲酸酯（Na_2L）的衍生物。通过微乳液法合成Eu（III）-L NCP，并且形态可以随着金属的变化而改变：配体比。 XRD结果表明，自组装的盘状NCPS表现出长距离有序结构。发光测量结果表明，所得NCPS不仅表现出EU（III）的典型荧光，而且还可以维持配体的固有荧光。

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《International Conference on Mechanical Science and Engineering》|2013年||共4页
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Cheng-an Tao; Yanan Lv; Lingqiang Meng; Huiping Liu; Zhihong Hu; Hui Zhu; Jianfang Wang;
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中图分类 TH11-53;
关键词
Coordination Polymer; Lanthanide; Luminescnet; Nanoscale; Microemulsion;

机译：协调聚合物;镧系;LUMINESCNET;纳米级;微乳液;

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2. A New 2D Europium(III) Coordination Polymer Based on 4-Bromoisophthalate Ligand: Synthesis, X-ray Structure, Luminescent and Magnetic Properties [J] . Ma Deyun, Wang Jun, Qin Liang, Journal of inorganic and organometallic polymers and materials . 2017,第5期

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4. Synthesis and Luminescent Properties of a Novel Nanoscale Eu(III)-Carboxylate Coordination Polymer [C] . Cheng-an Tao, Yanan Lv, Lingqiang Meng, International Conference on Mechanical Science and Engineering . 2013

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Synthesis and Luminescent Properties of a Novel Nanoscale Eu(III)-Carboxylate Coordination Polymer

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