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Catalytic reduction of N-nitrosodimethylamine by palladium/ iron bimetallic composite catalytic fiber

机译:钯/铁双金属复合催化纤维催化还原N-硝基甲酰亚甲胺

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The polypropylene (PP) fibers were chosen as substrate materials. Functional fibers containing iron were prepared by UV irradiation-coordination method, and then Pd/Fe bimetallic composite catalytic fibers were prepared by replacement reaction and used for the removement of N-nitrosodimethylamine (NDMA). The effect of monomer concentration, the pH of the reaction system and reaction temperature on NDMA catalytic degradation was investigated. The results indicate that the degradation rate of NDMA can reach 69.97% when the AA monomer concentration is 20%, which is the best catalytic reduction effect of composite catalytic fiber on NDMA. The pH of solution and reaction temperature can not greatly influence the catalytic reduction of NDMA.
机译:选择聚丙烯(PP)纤维作为底物材料。通过UV照射配合方法制备含有铁的功能纤维,然后通过替换反应制备Pd / Fe双金属复合催化纤维并用于去除N-亚硝二甲酰氨甲胺(NDMA)。研究了单体浓度,反应体系的pH和对NDMA催化降解的反应温度的影响。结果表明,当AA单体浓度为20%时,NDMA的降解率可以达到69.97%,这是NDMA上复合催化纤维的最佳催化还原效果。溶液和反应温度的pH不能大大影响NDMA的催化还原。

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