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Preparation of Patterned Graphene-ZnO Hybrid Nanoflower and Nanorods on ITO Surface

机译:图案化石墨烯 - ZnO杂交纳米辊和ITO表面纳米棒的制备

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Hybrid ZnO nanostructure with controlled morphology have been proved to enhance the physical and chemical properties of the material and used as photodiode and sensor. In this paper, hybrid graphene-ZnO nanoflower and nanorods have been successfully synthesized via a seed mediated method with micropatterned ZnO nanoseed treated with multilayer graphene (MLG) in a hydrothermal process. In typical process, the ZnO nanoseeds with and without resists were spin coated with a multilayer graphene prior to the growth process. The treated seed was then used to grow the ZnO nanostructures in the growth solution that contained equimolar (0.04 M) of zinc nitrate hexahydrate and hexamethylenetetramine. The growth process was carried out inside an autoclave at temperature 70 °C. The growth time was 4 h. It was proved that the MLG treatment on micropatterning substrate may induce new morphology formation of ZnO nanostructure. It is expected that the heteroepitaxy reaction occurred between the MLG and ZnO interface. This presence method can be used as an alternative approach to control the morphology of hybrid ZnO nanostructure growth.
机译:已证明具有受控形态的杂交ZnO纳米结构,以增强材料的物理和化学性质,并用作光电二极管和传感器。本文通过种子介导的方法成功地合成了杂交石墨烯-ZnO纳米λ和纳米棒,其在水热过程中用多层石墨烯(MLG)处理的微型解冻ZnO纳米糖。在典型的方法中,在生长过程之前用多层石墨烯旋涂具有和不具有抗蚀剂的ZnO纳米瘤。然后使用处理的种子在含有Equimolar(0.04m)的硝酸锌六水合物和六亚甲基丁胺的生长溶液中生长ZnO纳米结构。在高温70℃的高压釜内进行生长过程。生长时间为4小时。事实证明,对微型蚀刻基材的MLG处理可诱导ZnO纳米结构的新形态形成。期望杂痘反应发生在MLG和ZnO界面之间。该存在方法可以用作控制杂交ZnO纳米结构生长的形态的替代方法。

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