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Complexation of 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-7,14-dienium Bromide with Copper Salts

机译：用铜盐络合5,5,7,12,12,14-14-11-11-4-14-溴化铬的铜盐

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Copper complexes have been synthesized with 14-membered macrocyclic 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-7,14-dienium bromide (Me_6N_4H_4)Br_2 as ligand having six methyl groups and two double bonds located in diagonal position. These complexes were characterized by microelemental analysis, Fourier Transform Infrared (FTIR) and Ultraviolet-Visible (UV-VIS) spectroscopies. The chemical analysis and spectroscopic data is supported by chemical crystallographic study showed that one of the synthesized copper complex with CuCl_2 consists of [Cu(Me_6N_4H_2)] dication, two bromide counter anions and 2 water molecules of crystallisation. Thermogravimetry Analysis (TGA) showed that the complex is stable up to about 200°C before gradually decomposed up to 400°C.

机译：铜配合物已用14元大环5,5,5,7,12,12,14-六甲基-1,4,8,1-四氮杂环（Me_6N_4H_4）Br_2作为具有六个甲基的配体和位于对角线位置的两个双键。这些配合物的特征在于微精度分析，傅里叶变换红外（FTIR）和紫外 - 可见（UV-VIS）光谱。化学晶体研究支持化学分析和光谱数据表明，与CuCl_2的合成铜络合物中的一种由[Cu（ME_6N_4H_2）] DICT，两个溴化物抗衡阴离子和2水分子的结晶分子组成。热重量分析（TGA）显示复合物在逐渐分解至400℃之前稳定至约200℃。

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《UKM FST Postgraduate Colloquium》|2014年||共4页
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Ameera Aqeela Salleh Huddin; Bohari M. Yamin; Siti Fairus M. Yusoff;
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中图分类 G353.12-532;
关键词
Tetraaza; Macrocyclic; Copper Complexes;

机译：Tetraaza;宏环;铜复合物;

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机译：新型rac-5,5,7,12,12,14-六甲基-1,4,8,11-四氮杂环十四烷-4,11-二烯）硝酸双（叠氮基）钴（III）的合成，晶体结构和电化学性质甲醇溶剂合物
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3. N-rac-(5,7,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,14(1)-diene)copper(II): Structures of the perchlorate salt and a trinuclear tetracyanonickelato-bridged compound [J] . Curtis NF, Flood K, Robinson WT Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2006,第7期

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4. Complexation of 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-7,14-dienium Bromide with Copper Salts [C] . Ameera Aqeela Salleh Huddin, Bohari M. Yamin, Siti Fairus M. Yusoff UKM FST Postgraduate Colloquium . 2014

机译：用铜盐络合5,5,7,12,12,14-14-11-11-4-14-溴化铬的铜盐
5. The Influence of the Partial Replacing of Inorganic Salts of Calcium Zinc Iron and Copper with Amino Acid Complexes on Bone Development in Male Pheasants from Aviary Breeding [O] . Marian Flis, Dariusz Gugała, Siemowit Muszyński, 2019

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机译：用5,5,7,12,12,14-六甲基-1,4,8,11-四氮杂族静脉四-7,14-溴化物的Ni（II）络合物的合成与表征复合物

Complexation of 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-7,14-dienium Bromide with Copper Salts

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