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Efficient Nanocomposite formation of Acyrlo Nitrile Rubber by incorporation of Graphite and Graphene layers: Reduction in Friction and Wear Rate

机译:通过掺入石墨层和石墨烯层的高效纳米复合材料形成丙里罗腈橡胶:减少摩擦和磨损率

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Graphite (G) and its nano form Graphene (nG) are one of the most admirable fillers for incorporating multifunctional attributes in polymer/elastomer matrix. Use of such fillers in polymers/elastomers has enhanced their several properties and applicabilities. Acrylo Nitrile Butadiene Rubber (NBR) is a workhorse of the several industrial applications especially for automotive rubber products and in hydraulic area. Enhanced tribological properties of NBR are one of the crucial requirements for sealing applications. In this field we are first to report the anti wear study on NBR filled with Graphite and graphene layers. Sliding wear test showed that the wear parameters of NBR nanocomposites have significantly improved. The incorporation of graphene in NBR has reduced coefficient of friction 2.3 times more than that of graphite incorporated NBR. The reason for the same is proposed that the homogeneous distribution of nano layers in the elastomer matrix, the enhanced self lubrication of graphene, the favourable interface stability of composite contributed together to the improved wear properties of NBR nanocomposites. Along with it we have also investigated the effect of applied load, revolution per minute i.e., sliding speed on wear properties. The incorporation of fillers (G &nG) in NBR has also improved the hardness and tensile properties other than tribological properties. Electrical conductivity of graphene filled NBR has also been reported in comparison to graphite filled NBR and pristine NBR. The prepared graphene and the nanocomposites have also been fully characterized by different sophisticated techniques viz HR-TEM, FEG-SEM, Micro Raman, FT-IR. Improvement in such properties of NBR will definitely widen its role in multiple applications.
机译:石墨(G)及其纳米形式石墨烯(NG)是用于在聚合物/弹性体基质中掺入多功能属性的最令人钦佩的填充剂之一。在聚合物/弹性体中使用这种填料增强了它们的几种性能和应用。丙烯酰丁腈丁烯橡胶(NBR)是几种工业应用的主营主,特别是用于汽车橡胶制品和液压区域。 NBR的增强摩擦性质是对密封应用的关键要求之一。在该领域,我们首先报告填充石墨和石墨烯层的NBR的抗磨损研究。滑动磨损试验显示NBR纳米复合材料的磨损参数显着提高。 NBR中的石墨烯的掺入具有降低的摩擦系数,比石墨掺入NBR的2.3倍。同样的原因提出了一种相同的纳米层在弹性体基质中的均匀分布,石墨烯的增强的自润滑,复合材料的有利界面稳定性贡献在一起,以改善NBR纳米复合材料的耐磨性。除此之外,我们还研究了施加负荷,旋转每分钟的效果,即磨损性能的滑动速度。填料(G&NG)在NBR中的掺入还提高了除摩擦学特性之外的硬度和拉伸性能。与石墨填充的NBR和原始NBR相比,还报道了石墨烯填充NBR的电导率。制备的石墨烯和纳米复合材料还通过不同的复杂技术viz hr-tem,feg-sem,微拉曼,FT-IR完全表征。 NBR此类属性的改善肯定会扩大其在多种应用中的作用。

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