首页> 外文会议>International Conference on Machinery, Materials and Information Technology Applications >Synthsis and Photophysical Properties of a copper (I) complex emitting material containing 1-(9H-fluoren-2-yl)-1H-imidazo4,5-f1,10phenanthroline ligand
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Synthsis and Photophysical Properties of a copper (I) complex emitting material containing 1-(9H-fluoren-2-yl)-1H-imidazo4,5-f1,10phenanthroline ligand

机译:含有1-(9h-氟化烯-2-基)-1H-咪唑4,5-F 1,10菲咯啉配体的铜(I)铜(I)复合物发光材料的合成和光物理性质

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A new copper(I) complex, [Cu(βFlu-imPhen)(POP)]PF_6, where β-Flu-imPhen = 1-(9H-fluoren-2-yl)-1H-imidazo[4,5-f][1,10]phenanthroline, POP=bis(2-diphenylphosphanyl)ether, was synthesized and characterized. The corresponding photophysical properties were investigated using UV-vis and emission spectrometry. The weak absorption bands were observed in the region of 350-400nm for complex [Cu(βFlu-imPhen)(POP)]PF_6, while the emission maximum was located at 584 nm upon excitation at 320 nm in PMMA films.
机译:一种新的铜(I)复合物,[Cu(βflu-imphen)(pop)] pf_6,其中β-流感 - imphen = 1-(9h-芴-2-基)-1h-inmidazo [4,5-f] [1,10]菲素,Pop =双(2-二苯基膦基)醚,合成并表征。使用UV-Vis和发射光谱法研究了相应的光学性质。在350-400nm的区域中观察到弱吸收带,用于复合[Cu(βFlu-imphen)(POP)] PF_6,而在PMMA膜中的320nm激发时,发射最大值位于584nm处。

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