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Simple Experiments Giving Deep Insights into Capacity Fade and Capacity Loss Mechanisms of Li Battery Materials - (PPT)

机译:简单的实验,深入了解Li电池材料的容量褪色和容量损失机制 - (PPT)

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In full cells, anode and cathode may contribute to capacity fade and "capacity loss". Electrolyte oxidation makes a minor contribution to low Coulombic efficiencies of cathodes at high voltage. The type of active material, rather than the cut-off and operation potentials determine HV performance. The practical cathode capacity should be derived from the charge capacity, and not from the discharge capacity. The contribution of Active Lithium Losses (Q_(ALL)) to Irrev. Capacities (Q_(IRR) and Q_(AIC)) can be determined → "IRLC-Method". Simple, but in the community uncommon electrochemical techniques reveal that "common wisdom" may need a thorough re-thinking.
机译:在完整的细胞中,阳极和阴极可以有助于容量衰落和“容量损耗”。电解质氧化对高电压下阴极的低库仑效率进行了微小的贡献。活性材料的类型,而不是截止和操作电位确定HV性能。实际的阴极容量应源于充电容量,而不是从放电容量中得出。活性锂损失的贡献(Q_(全))给Inrev。可以确定容量(Q_(irr)和Q_(AIC))→“IRLC方法”。简单,但在社区中罕见的电化学技术揭示了“普通智慧”可能需要彻底重新思考。

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