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Decoloured Novatein and PLA Blends Compatibilized with Itaconic Anhydride

机译:用衣康酸酐与衣康酸酐相容的脱色新蛋白和PLA混合物

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Poly (lactic acid) (PLA) was modified through free radical grafting of itaconic anhydride to create reactive side-chain groups. Modified PLA was blended with Decoloured Novatein (DNTP), a thermoplastic protein material using reactive extrusion to produce a degradable material with improved properties compared to neat Decoloured Novatein. Varying ratios of blends were prepared. DNTP/PLA blends was found to increase tensile strength between 22% to 538% and modulus between 201 GPa to 3193 GPa, whereas the strain at break decreased between 80% to 94% depending on the blend ratio. The glass transition temperature of the blends which was measured as the tan δ peak, also revealed an increase when compared to neat DNTP. Scanning electron microscope revealed an enhanced interfacial adhesion between the two phases in the blends with PLA-g-IA suggesting a more homogenous microstructure. The results show the possibility and feasibility of blending DNTP with PLA for use in agricultural and packaging applications.
机译:通过自由基移植衣康酸酐来改变聚(乳酸)(PLA)以产生反应性侧链基团。改性PLA与脱色的新蛋白(DNTP)混合,使用反应性挤出的热塑性蛋白质材料,与整齐的脱色的新生素相比,具有改善的性能,具有改善的性能。制备不同的混合物比例。发现DNTP / PLA混合物在201%至538%的抗拉强度增加到201%至538%,而201GPa至3193GPa之间的模量,而断裂菌株根据混合物比率降低80%至94%。与整齐的DNTP相比,测量的混合物的玻璃化转变温度也显示出增加的增加。扫描电子显微镜揭示了与PLA-G-Ia中共混物中两相之间的增强的界面粘合性,提示更均匀的微观结构。结果表明,将DNTP与PLA混合用于农业和包装应用的可能性和可行性。

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