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Controlled shear stress method to measure yield stress of highly filled polymer melts

机译:控制剪切应力法测量高填充聚合物熔体的屈服应力

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Powder injection moulding (PIM) is a multi-stage process to manufacture metallic or ceramic complex, functional parts in large quantities and with high material requirements. The flow in PIM filling process is a complicated non-isothermal problem with viscoelasticity effects and instabilities. The exact description of the whole process of the flow is very difficult. The existence of a yield stress on PIM-feedstock depends on particle interactions within the polymer matrix. Further factors, like powder loading and dispersion during the measurements, are influencing the rheological characterisation of PIM-feedstocks. Additionally, inertial and gravitational effects can have an influence for systems with a very low viscous matrix. Quantifying yield stress, however, must be done carefully because the value obtained depends on the analytical technique used. Knowing the flow behaviour of PIM-feedstock is necessary for successful filling simulation of PIM. In this context, the yield behaviour of a stainless steel feedstock was studied using a plate-plate controlled stress rheometer (CSS). The rheological data obtained from CSS were compared to the measurement made on a slit-die rheometer in controlled shear rate mode (CSR). Controlled stress rheology is more sensitive and provides more accurate results of yield stress than CSR.
机译:粉末注射成型(PIM)是一种多级工艺,用于制造大量的金属或陶瓷复合物,功能性部位,具有高材料要求。 PIM填充过程中的流动是一种复杂的非等温问题,具有粘弹性效应和稳定性。流动整个过程的确切描述非常困难。 PIM原料屈服应力的存在取决于聚合物基质内的颗粒相互作用。在测量期间的粉末装载和分散等其他因素,正在影响PIM原料的流变性表征。另外,惯性和引力效应可以对具有非常低的粘性基质的系统产生影响。然而,必须小心地进行量化屈服应力,因为所获得的值取决于所使用的分析技术。知道PIM-FeedStock的流动是为了成功填充PIM的模拟所必需的。在这种情况下,使用板材控制应力流变仪(CSS)研究不锈钢原料的屈服行为。将CSS获得的流变数据与在受控剪切速率模式(CSR)中的狭缝模流仪上进行的测量进行了比较。受控应力流变学更敏感,并提供比CSR的屈服应力的更准确的结果。

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