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Synthesis of Novel Tridentate PNP Ligands Having Secondary Phosphine Oxide Moieties and Their Application to Oxygenation of a Benzylpalladium Complex

机译：具有二次磷化膦部分的新型三齿PNP配体的合成及其在苄基钯络合物氧合中的应用

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Investigation on the reactivity of transition metal hydrocarbyl complexes toward molecular oxygen contributes to the development of catalytic oxygenation of hydrocarbons to oxygen-containing organic compounds. We have previously reported that the oxygenation of a benzyl ligand in [PdBnCl(cod)] was dramatically accelerated by the addition of mono- or bidentate secondary phosphine oxides (SPOs), affording either BnOOH or BnOH selectively as a main oxygenated product, depending on the reaction conditions.

机译：对分子氧的过渡金属烃基复合物反应性的研究有助于烃催化氧合的含氧有机化合物的发展。我们之前报道，通过加入单齿或双硫化物二次膦氧化物（SPO），通过选择性为主要含氧产品，通过添加单次或双硫化物二次磷酸（SPO），显着加速苄基配体在[PDBNCL（COD）]中的氧合急促加速。反应条件。

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来源
《日本化学会春季年会講演予稿集》|2018年|1 CD-ROM|共1页
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Sayaka Oka; Karen Miya; Yasutaka Kataoka;
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中图分类石油化学工业;
关键词
Oxygenation; Secondary Phosphine Oxides; Tridentate PNP Ligands; Molecular Oxygen; Benzyl Ligand;

机译：氧合;二次磷酸;三齿PNP配体;分子氧;苄基配体;

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1. Neodymium dihalide complexes with a tridentate amidinate phosphine oxide ligand: synthesis, structure, and catalytic activity in isoprene polymerization [J] . Tolpygin A. O., Linnikova O. A., Kovylina T. A., Russian Chemical Bulletin . 2019,第1期

机译：钕二卤化物配合物与三乙酸盐氧化膦配体：异戊二烯聚合中的合成，结构和催化活性
2. Novel carborane complexes of ruthenium with tridentate phosphine ligands: Synthesis and application in Atom Transfer Radical Polymerization [J] . Kaltenberg Alexander A., Somov Nikolay V, Malysheva Yulia B., Journal of Organometallic Chemistry . 2020,第1期

机译：具有三乙酸膦酸钌的新型碳甲磺酸盐配合物：原子转移自由基聚合的合成及应用
3. Synthesis and structure of tridentate bis(phosphinic amide)-phosphine oxide complexes of yttrium nitrate. Applications of ~(31)P,~(89)Y NMR methods in structural elucidation in solution [J] . Popovici C., Fernández I., O?a-Burgos P., Dalton transactions: An international journal of inorganic chemistry . 2011,第25期

机译：硝酸钇三齿双（次膦酰胺）-氧化膦配合物的合成与结构。〜（31）P，〜（89）Y NMR方法在溶液结构解析中的应用
4. Synthesis of Novel Tridentate PNP Ligands Having Secondary Phosphine Oxide Moieties and Their Application to Oxygenation of a Benzylpalladium Complex [C] . Sayaka Oka, Karen Miya, Yasutaka Kataoka 日本化学会春季年会講演予稿集 . 2018

机译：具有二次磷化膦部分的新型三齿PNP配体的合成及其在苄基钯络合物氧合中的应用
5. The synthesis, reactivity and characterization of highly unusual, and unsaturated ruthenium compounds supported by bulky "PNP" tridentate "pincer" ligands. [D] . Groves, Amy Nichole. 2009

机译：庞大的“ PNP”三齿“钳”配体支持的高度不寻常的不饱和钌化合物的合成，反应性和表征。
6. New phosphine-diamine and phosphine-amino-alcohol tridentate ligands for ruthenium catalysed enantioselective hydrogenation of ketones and a concise lactone synthesis enabled by asymmetric reduction of cyano-ketones [O] . José A Fuentes, Scott D Phillips, Matthew L Clarke 2012

机译：用于钌催化酮的对映选择性氢化的新膦二胺和膦氨基氨基醇三齿配体以及通过不对称还原氰基酮实现的简洁内酯合成
7. Synthesis and structure of tridentate bis(phosphinic amide)-phosphine oxide complexes of yttrium nitrate. Applications of (31)P,(89)Y NMR methods in structural elucidation in solution [O] . Fernández Ignacio, Roces Laura, García-Granda Santiago, 2012

机译：硝酸钇三齿双（次膦酰胺）-氧化膦配合物的合成与结构。（31）P，（89）Y NMR方法在溶液结构解析中的应用
8. Tris (phenyl (difluorophosphino) amino)phosphine (P(N(C6H5)PF2)3), a Novel Tridentate Strong pi-Accept-or Ligand Forming Cage Chelates. Crystal Structure of the Chelate Complex P(N(C6H5)PF2)3Mo(CO)3 [R] . Brown, G. M., Finholt, J. E., King, R. B., 1981

机译：三（苯基（二氟膦基）氨基）膦（p（N（C6H5）pF2）3），新型三齿强π-接受 - 或配体形成笼螯合物。螯合物p（N（C6H5）pF2）3mo（CO）3的晶体结构

Synthesis of Novel Tridentate PNP Ligands Having Secondary Phosphine Oxide Moieties and Their Application to Oxygenation of a Benzylpalladium Complex

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