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Synthesis of α-Fluoroimines from Copper-Catalyzed Reactions of Diarylacetylenes and N-Fluorobenzenesulfonimide

机译：二芳基乙烯基铜催化反应的α-氟杂质的合成，N-氟苯磺酰胺

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Organofluorine molecules are important in pharmaceutical and agriculture chemistry because they have enhanced binding affinity and greater bioactivity. Difunctionalization of unsaturated bonds with fluorinating reagents has been regarded as an efficient route to vic-difunctional organic fluorides.

机译：有机氟分子在制药和农业化学中是重要的，因为它们具有增强的结合亲和力和更大的生物活性。用氟化试剂的不饱和键的双官能化被认为是与VIC-双官能有机氟化物的有效途径。

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来源
《日本化学会春季年会講演予稿集》|2018年|1 CD-ROM|共1页
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Shu Jan Yip; Tetsushi Yoshidomi; Kei Murakami;
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正文语种
中图分类石油化学工业;
关键词
Copper catalyst; Imine; Fluorine; Alkyne;

机译：铜催化剂;亚胺;氟;alkyne.;

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专利

1. Synthesis of alpha-Fluoroimines by Copper-catalyzed Reaction of Diarylacetylenes and N-Fluorobenzenesulfonimide [J] . Yip Shu Jan, Yoshidomi Tetsushi, Murakami Kei, Chemistry Letters . 2018,第3期

机译：二芳基乙炔和N-氟苯磺酰胺的铜催化反应合成α-氟喹肟
2. Synthesis of Benzoquinolizinium Salts by Rh(III)-Catalyzed Cascade Double N-Annulation Reactions of Allylamines, Diarylacetylenes, and HBF4 [J] . Han Ye Ri, Shim Su-Hyang, Kim Dong-Su, Organic letters . 2017,第11期

机译：RH（III）合成苯醌盐（III） - 催化级联双N环含有烯丙胺，二芳基乙炔和HBF4
3. Palladium nanoparticles catalyzed Sonogashira reactions for the one-pot synthesis of symmetrical and unsymmetrical diarylacetylenes [J] . Pavan Kumar Mandali, Dillip Kumar Chand Catalysis Communications . 2014,第Null期

机译：钯纳米粒子催化Sonogashira反应一锅合成对称和不对称的二芳基乙炔
4. Synthesis of α-Fluoroimines from Copper-Catalyzed Reactions of Diarylacetylenes and N-Fluorobenzenesulfonimide [C] . Shu Jan Yip, Tetsushi Yoshidomi, Kei Murakami 日本化学会春季年会講演予稿集 . 2018

机译：二芳基乙烯基铜催化反应的α-氟杂质的合成，N-氟苯磺酰胺
5. Synthesis of Multifunctional Organoboron Compounds by Copper-Catalyzed Enantioselective Reactions [D] . Huang, Zeyu. 2017

机译：铜催化的对映选择性反应合成多官能有机硼化合物
6. Copper-Catalyzed Three- Five- or Seven-Component Coupling Reactions: The Selective Synthesis of Cyanomethylamines NN-Bis(Cyanomethyl)Amines and NN-Bis(Cyanomethyl)Methylenediamines Based on a Strecker-Type Synthesis [O] . Norio Sakai, Nobuaki Takahashi, Daiki Inoda, 2013

机译：铜催化的三元或五元或七元偶联反应：基于Strecker型合成的氰基甲胺NN-双（氰基甲基）胺和NN-双（氰基甲基）亚甲基二胺的选择性合成
7. The regio- and stereospecific synthesis of diarylpropenyllithium compounds from dimethylamino- and dimethylaminomethyl-substituted diarylacetylenes via transmetallation reactions involving diarylpropenylmagnesium and -tin compounds [O] . Richard W.M. Ten Hoedt, Gerard Van Koten, Jan G. Noltes 1979

机译：通过涉及二芳基丙基镁胺和-Tin化合物的透过透过透过透过透过透过透过透过透过透过透过透过透过透过透过透过透过透过甲氨基和二甲基氨基甲基取代的二芳基亚乙炔的重组和立体合成

Synthesis of α-Fluoroimines from Copper-Catalyzed Reactions of Diarylacetylenes and N-Fluorobenzenesulfonimide

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