• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文会议>日本化学会春季年会講演予稿集 >Pd-Catalyzed Allylation of Aldehydes with Silyl-Substituted Allyl Acetates Proceeding through a Migration of Substituents on Silyl Group
【24h】

Pd-Catalyzed Allylation of Aldehydes with Silyl-Substituted Allyl Acetates Proceeding through a Migration of Substituents on Silyl Group

机译：通过迁移甲硅烷基对甲硅烷基的含有甲硅烷基取代的烯丙基乙酸盐的PD催化的醛溶液

获取原文
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Thermal 1,2-shifts of a group from the α-acetoxysilanes is known to occur between 200 and 270 °C.1 The reaction usually takes place with almost complete inversion of configuration, and shows good preference for phenyl over methyl migration. As synthetic routes to acylsilanes are limited, thermal rearrangements of α-acetoxysilanes have not yet reached a point where it is a practical and general synthetic methods. We report herein that palladium-catalyzed allylation reaction of aldehydes with organosilyl-substituted allyl acetates that involves alkyl or aryl group migration from reactant silanes.
机译：已知来自α-乙酰氧西硅烷的基团的热量1,2-偏移在200至270℃之间发生反应通常用几乎完全的构型倒置进行，并且对苯基进行良好的偏爱甲基迁移。由于对酰基硅烷的合成途径有限，α-乙酰氧西硅烷的热重排尚尚未达到一种实用和一般的合成方法的点。我们在本文中报告，醛催化醛与有机玻璃取代的烯丙基乙酸酯的烯丙基反应，其涉及从反应物硅烷迁移的烷基或芳基偏移。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号