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首页> 外文会议>日本化学会春季年会講演予稿集 >Structural Analysis of Soft Azobenzene Crystal and Its Mechanical Self-Oscillation under Continuous Blue Light Irradiation
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Structural Analysis of Soft Azobenzene Crystal and Its Mechanical Self-Oscillation under Continuous Blue Light Irradiation

机译：绵延蓝光照射下软偶氮苯晶体的结构分析及其机械自振荡

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摘要

Realization of sustainably and autonomously working materials is the most important target of current chemistry. To realizing such dynamics, dissipative self-organization is required. Previously, we reported self-oscillatory flipping motion of co-crystal of oleic acid and azobenzene derivative(1) under continuous blue-light irradiation.1) It was the first report of mechanical motion of non-living material with dissipative self-organization of chemical reaction and crystalline phase transition. However, crystal structure of the co-crystal has not been clear. Recently, we also succeeded to demonstrate self-oscillatory flipping motion of crystal of 1 without fatty acids, and to reveal the crystal structure of the original phase.
机译：可持续和自主工作材料的实现是当前化学的最重要目标。为了实现这种动态，需要耗散自我组织。以前，我们报道了在连续蓝光照射下的油酸和偶氮烯衍生物（1）的共振荡翻转运动.1）这是具有耗散自组织的非生物材料机械运动的第一报告化学反应和结晶相转变。然而，共晶的晶体结构尚未清楚。最近，我们也成功地展示了1个没有脂肪酸的1的晶体的自振荡，并且揭示了原始相的晶体结构。

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