Adatom Surface Modification of Metal Nanoparticle Electrodes Though Underpotential Deposition for CO_2 Electroreduction Catalysis

机译：金属纳米颗粒电极的ADATOM表面改性虽然CO_2电催化催化下电沉积

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The electrocatalytic CO_2 reduction reaction to form higher order carbon-coupled products is a complex interplay of CO binding energies, kinetic rate-constant branching ratios, CO_2 solubility, and pH gradients. The result of this wide, and often uncontrolled parameter space is a distribution of CO_2RR products, especially in carbon-coupled reactions. Designing electrocatalysts that promote any of these parameters individually is an attractive route to not only build selective CO_2RR catalysts, but also to provide the framework of design principals for selective electrocatalysis. To this end, systematically varying the electrode kinetics of CO_2 reduction reactions on model system substrates through minor surface modifications is an informative approach for understanding this complicated reaction and how certain products can be expressed or suppressed.

机译：形成高阶碳偶联产物的电催化CO_2还原反应是CO结合能量，动力率 - 恒定支化比，CO_2溶解度和pH梯度的复杂相互作用。这一宽，通常不受控制的参数空间是CO_2RR产品的分布，尤其是碳偶联反应。设计促进任何这些参数的电催化剂单独地是一个有吸引力的路线，不仅是构建选择性CO_2RR催化剂的途径，还提供了用于选择性电常分的设计主体框架。为此，通过轻微的表面修饰系统地改变CO_2还原反应的电极动力学是模型系统衬底上的一种信息，以了解这种复杂反应以及如何表达或抑制某些产品。

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《Pacific Rim Meeting on Electrochemical and Solid-State Science》|2020年|1761-2200p|共1页
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Mike Carroll;
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1. A New Approach to Structural Study of Underpotential Deposition of Adatoms on the Electrode Surface, Platinum (111) [J] . Joseph W. Ndieyira, Evans D. Chabala, Trevor Rayment Discovery and Innovation . 2005,第1a2期

机译：电极表面铂（111）上负原子沉积的结构研究的新方法
2. Modification of Electrode Surfaces: Deposition of Thin Layers of Polypyrrole−Au Nanoparticle Materials Using a Combination of Interphase Synthesis and Dip-in Method [J] . Marianna Gniadek Sylwia Modzelewska Mikolaj Donten and Zbigniew Stojek Analytical Chemistry . 2010,第2期

机译：电极表面的改性：结合相合成和浸入法沉积的聚吡咯-金纳米颗粒材料的薄层
3. Modification of Electrode Surfaces: Deposition of Thin Layers of Polypyrrole-Au Nanoparticle Materials Using a Combination of Interphase Synthesis and Dip-in Method [J] . Marianna Gniadek, Sylwia Modzelewska, Mikolaj Donten, Analytical chemistry . 2010,第2期

机译：电极表面的改性：结合相合成和浸入法沉积的聚吡咯-金纳米颗粒材料的薄层
4. Adatom Surface Modification of Metal Nanoparticle Electrodes Though Underpotential Deposition for CO_2 Electroreduction Catalysis [C] . Mike Carroll Pacific Rim Meeting on Electrochemical and Solid-State Science . 2020

机译：金属纳米颗粒电极的ADATOM表面改性虽然CO_2电催化催化下电沉积
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机译：钌的自指导有机金属沉积：直接甲醇燃料电池中甲醇电氧化的双金属，钌原子原子修饰的铂表面的制备，表征和评估。
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机译：电极表面电沉积过程中金属纳米颗粒的形核聚集生长和脱离
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机译：高度分散的Pt纳米颗粒在高表面积电极主体上的原子层沉积，用于电化学促进催化
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机译：欠电位金属沉积及固体电极痕量分析的基础研究。

Adatom Surface Modification of Metal Nanoparticle Electrodes Though Underpotential Deposition for CO_2 Electroreduction Catalysis

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