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Eutectic Mixture of Iron(III) Chloride and Acetamide - Physicochemical Properties, Chemical Speciation, and Electrodeposition of Iron

机译:铁(III)氯化物和乙酰胺 - 物理化学性质,化学品种和铁的电沉积的共晶混合物

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The electrodeposition of iron alloys is a significant research topic, owing to the potential applications such as corrosion/wear-resistant coatings, magnetic thin films, and catalyst electrodes. Although aqueous electrolytes have been mostly used for electrodeposition, vigorous hydrogen evolution on the cathode can lead to hydrogen embrittlement and precipitation of metal hydroxides. In addition, less noble elements such as aluminum and silicon cannot be co-deposited from aqueous electrolytes due to the limited electrochemical window.
机译:由于诸如腐蚀/耐磨涂层,磁性薄膜和催化剂电极等潜在的应用,铁合金的电沉积是一个重要的研究题目。 虽然水性电解质主要用于电沉积,但阴极上的剧烈氢化可以导致金属氢氧化物的氢脆和沉淀。 另外,诸如铝和硅的较少的惰性元素不能由由于电化学窗口的有限电解质的水性电解质共沉积。

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