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POLYMERIC AMINES: ROLE IN BIOSILICIFICATON AND POTENTIAL IN NANOTECHNOLOGIES

机译:高分子胺类:在细菌生命中的作用和在纳米技术中的潜力

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Condensation of silicic acid was studied in the presence of poly(vinylamine) fractions (238-11000 units). The reaction results in soluble nanoparticles or composite precipitates depending on polymerization degree of the organic polymer and pH. The structure of the nanoparticles in solution was close to a microgel for high-molecular weight polymers or to hyper-branched systems when the extent of polymerization was below 1000. Silicic acid exists in these particles in slightly polymerized form in contrast to silica obtained without polymers. We consider polymer - poly(silicic acid) nanoparticles as a new silica precursor for the design of silica and composite materials. We suspect that a similar method of storing silicic acid in an active state is used in silicifying organisms, at least in diatom algae.
机译:在聚(乙烯胺)馏分(238-11000单位)存在下,研究了硅酸的缩合反应。反应产生可溶的纳米颗粒或复合沉淀,这取决于有机聚合物的聚合度和pH。当聚合度低于1000时,溶液中的纳米颗粒的结构接近于高分子量聚合物的微凝胶或超支化体系。与不含聚合物的二氧化硅相比,硅酸以稍微聚合的形式存在于这些颗粒中。我们认为聚合物-聚(硅酸)纳米粒子是用于设计二氧化硅和复合材料的新型二氧化硅前体。我们怀疑在硅化生物中,至少在硅藻中,使用了一种类似的以活性状态存储硅酸的方法。

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