Different site potentials for amine and imine in the emeraldine-base polymer

Zhang Y.; Liu J.

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Different site potentials for amine and imine in the emeraldine-base polymer

机译：翡翠碱聚合物中胺和亚胺的位点电位不同

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Considering a site-potential difference between amine and imine, we investigate the self-consistent-variation ground and defect state of the emeraldine-base polymer in the framework of an extended Ginder-Epstein model. The results show that the model with a site-potential difference alpha(im) - alpha(am) = 0.8 eV can reproduce most of the observed data in the polymer. The 1.4 and 0.9 eV peaks of photoinduced absorption in the EB polymer can be attributed to the charged combined polarons P- and P+, respectively. [References: 21]

机译：考虑到胺和亚胺之间的位势差，我们在扩展的Ginder-Epstein模型的框架下研究了基于翡翠碱的聚合物的自洽变异基和缺陷状态。结果表明，位势差为alpha（im）-alpha（am）= 0.8 eV的模型可以重现聚合物中观察到的大多数数据。 EB聚合物中光诱导吸收的1.4和0.9 eV峰可分别归因于带电的组合极化子P-和P +。 [参考：21]

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《Physica status solidi, B. Basic research》 |2000年第1期|共8页
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Zhang Y.; Liu J.;
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正文语种 eng
中图分类固体物理学;
关键词
Ring-torsion soliton; Electronic-properties; Conduction mechanism; Oxidized polyaniline; Defect states; Disorder; Polarons; Model; Angle;

机译：环扭孤子;电子性质;导电机理;氧化聚苯胺;缺陷态;无序;极化子;模型;角度;

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1. Different site potentials for amine and imine in the emeraldine-base polymer [J] . Zhang Y., Liu J. Physica status solidi, B. Basic research . 2000,第1期

机译：翡翠碱聚合物中胺和亚胺的位点电位不同
2. Polaron states and associated optical absorption in an emeraldine-base polymer with 4n +/- 1 nitrogen sites [J] . Zhang Y., Liu J., Yu L. Physica status solidi, B. Basic research . 2003,第2期

机译：具有4n +/- 1个氮位的翡翠碱聚合物中的极化子态和相关的光吸收
3. Ni complexes of N2S ligands with amine/imine and amine/amide donors with relevance to the active site of Ni superoxide dismutase [J] . Senaratne Nilmini K., Mwania Tom M., Moore Curtis E., Inorganica Chimica Acta . 2018,第期

机译：N 2S配体与胺/亚胺和胺/酰胺供体的Ni络合物，其与Ni超氧化物歧化酶的活性位点相关性
4. Bis(benzimidazole)amine Vanadium Catalysts for Olefin Polymerization and Copolymerization:Thermally Robust, Single-Site Catalysts Activated by Simple Alkylaluminum Reagents [C] . Atanas K. Tomov, Vernon C. Gibson, Damien Zaher Division of Polymeric Material: Science and Engineering American Chemical Society meeting . 2004

机译：BIS（苯并咪唑）胺钒催化剂用于烯烃聚合和共聚：通过简单的烷基铝试剂激活的热稳健，单现场催化剂
5. Chain transfer processes in single-site olefin polymerization: Effects of organosilanes and amines as chain transfer agents. [D] . Amin, Smruti Bharat. 2007

机译：单中心烯烃聚合中的链转移过程：有机硅烷和胺作为链转移剂的作用。
6. Glycosylated aniline polymer sensor: Amine to imine conversion on protein–carbohydrate binding [O] . Zhe Wang, Chunyan Sun, Giri Vegesna, -1

机译：糖基化苯胺聚合物传感器：胺对蛋白质 - 碳水化合物结合的亚胺转化
7. Glycosylated aniline polymer sensor: Amine to imine conversion on protein–carbohydrate binding [O] . Zhe Wang, Chunyan Sun, Giri Vegesna, 2013

机译：糖基化苯胺聚合物传感器：胺对蛋白质 - 碳水化合物结合的亚胺转化
8. Polymerization of Azaethylenes (Imines) and Aza-1,3-Dienes. Potential Reactive Monomers [R] . Hall, H. K. 1988

机译：azaethylenes（亚胺）和氮杂-1,3-二烯的聚合。潜在的反应性单体

Different site potentials for amine and imine in the emeraldine-base polymer

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