Hierarchical Self-Assembly Structures of POSS-Containing Polypeptide Block Copolymers

机译：含POSS的多肽嵌段共聚物的分层自组装结构

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In this study,we used a combination of atom transfer radical polymerization,ring opening polymerization,and click chemistry to synthesize new organic/inorganic macromolecular self-assembling building blocks of polystyrene-b-poly(γ-propargyl-l-glutamate-g-polyhedral oligomeric silsesquioxane) [PS-b-(PPLG-g-POSS)].The incorporation of the PS and POSS units enhanced the a-helical conformation in the solid state,as determined using Fourier transform infrared (FTIR) spectroscopy and wide-angle X-ray diffraction (WAXD).

机译：在这项研究中，我们结合了原子转移自由基聚合，开环聚合和点击化学的方法，合成了新型的有机/无机大分子自组装聚苯乙烯-b-聚（γ-炔丙基-l-谷氨酸-g-多面体低聚倍半硅氧烷）[PS-b-（PPLG-g-POSS）]。PS和POSS单元的结合增强了固态的a螺旋构象，这是通过傅里叶变换红外（FTIR）光谱和角X射线衍射（WAXD）。

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来源
《Proceedings of the Sixth Asia-Europe symposium on processing and properties of reinforced polymers》|2013年|96|共1页
会议地点 Wuhan(CN)
作者
Y.C.Lin; S.W.Kuo;
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作者单位

Department of Materials and Optoelectronic Science, Sun Yat-Sen University, Kaohsiung, 804, Taiwan, China;

Department of Materials and Optoelectronic Science, Sun Yat-Sen University, Kaohsiung, 804, Taiwan, China;

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会议组织
原文格式 PDF
正文语种 eng
中图分类高分子化学（高聚物）;
关键词
POSS; Nanocomposites; Self-Assembly; Polypeptide;

机译：POSS；纳米复合材料；自组装；多肽;

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1. Self-assembly of POSS-containing block copolymers: Fixing the hierarchical structure in networks [J] . Libor Mat?jka, Miroslav Janata, Josef Ple?til, Polymer: The International Journal for the Science and Technology of Polymers . 2014,第1期

机译：含POSS的嵌段共聚物的自组装：固定网络中的层次结构
2. Hydrogen Bond Interactions Mediate Hierarchical Self-Assembly of POSS-Containing Block Copolymers Blended with Phenolic Resin [J] . Chiou Chin-Wei, Lin Yung-Chih, Wang Lei, Macromolecules . 2014,第24期

机译：氢键相互作用介导含有POSS的酚醛树脂嵌段共聚物的分层自组装
3. Hierarchical Self-Assembled Structures from POSS-Containing Block Copolymers Synthesized by Living Anionic Polymerization [J] . Hirai T, Leolukman M, Jin S, Macromolecules . 2009,第22期

机译：活性阴离子聚合合成含POSS的嵌段共聚物的分层自组装结构
4. Hierarchical Self-Assembly Structures of POSS-Containing Polypeptide Block Copolymers [C] . Y.C.Lin, S.W.Kuo Asia-Europe symposium on processing and properties . 2013

机译：含有含有多肽嵌段共聚物的分层自组装结构
5. Toward Hierarchical Material Design via Block Copolymers in a Protic Ionic Liquid: Self-assembly, Functionalization, Device Fabrication, and Commercialization [D] . Xie, Ru. 2018

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6. Solvent effects leading to a variety of different 2D structures in the self-assembly of a crystalline-coil block copolymer with an amphiphilic corona-forming block [O] . Shaofei Song, Qing Yu, Hang Zhou, 2020

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7. Block Copolymers Containing Conjugated Polymer and Polypeptide Sequences: Synthesis and Self-Assembly of Electroactive and Photoactive Nanostructures [O] . -1

机译：含有缀合聚合物和多肽序列的嵌段共聚物：电活性和光活性纳米结构的合成和自组装

Hierarchical Self-Assembly Structures of POSS-Containing Polypeptide Block Copolymers

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