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Rapid and sensitive determination of benzoapyrene in black ginseng using fluorescence detector and high performance liquid chromatography-tandem mass spectrometry

机译：荧光检测器-高效液相色谱-串联质谱法快速灵敏地测定人参中的苯并a py

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摘要

Black ginseng is produced by steaming a ginseng root followed by drying repeatedly 9 times during the process and it is changed to be black color, so it is known that a black ginseng has more contents of saponins than red ginseng. However a fake black ginseng which is produced to be black color at high temperature in a short period of time generate carcinogenic benzo[a]pyrene(BaP) through the process. In this year, maximum residue level(MRL) for BaP was established to 2 μg/kg in black ginseng and more sensitive method was developed to quantitatively analyze the BaP by high performance liquid chromatography (HPLC) coupling with florescence detector and tandem mass spectrometry (atmospheric pressure chemical ionization-MS/MS). Chromatographic separation was performed on a Supelcosil™ LCPAH column (3 μm, 3 mm × 50 mm). Mobile phase A was water and mobile phase B was acetonitrile. BaP was exactly separated from other 15 polycyclic aromatic hydrocarbons (PAHs) which have been selected as priority pollutants by the US Environmental Protection Agency (EPA). Linearity of detection was in the range of 0.2～20 μg/kg and limit of detection (LOD) for BaP was lower than 0.1 μg/kg, limit of quantification (LOQ) was 0.2 μg/kg. The recovery of Bap was 92.54%±6.3% in black ginseng.
机译：黑参是通过蒸人参根，然后在此过程中反复干燥9次而产生的，并且变黑为黑色，因此已知黑参中皂苷的含量比红参中的含量高。然而，假冒的人参在短时间内在高温下会变成黑色，会在此过程中产生致癌的苯并[a] py（BaP）。今年，黑参中BaP的最大残留量（MRL）确定为2μg/ kg，并开发了更灵敏的方法，通过高效液相色谱（HPLC）结合荧光检测器和串联质谱法定量分析BaP（大气压化学电离-MS / MS）。在Supelcosil™LCPAH色谱柱（3μm，3 mm×50 mm）上进行色谱分离。流动相A是水，流动相B是乙腈。 BaP与其他15种多环芳烃（PAH）完全分离，后者已被美国环境保护署（EPA）选择为优先污染物。检测线性在0.2〜20μg/ kg范围内，BaP的检测限（LOD）低于0.1μg/ kg，定量限（LOQ）为0.2μg/ kg。黑参中Bap的回收率为92.54％±6.3％。

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  • 来源
  • 会议地点 Baltimore MD(US)
  • 作者

    Hyun-jeong Cho; Hye-jin Kim; Byeong-cheol Son; Dong-keun Jo; Byung-lim Cho;

  • 作者单位

    Division of Safety Analysis, Experiment Research Institute National Agricultural Products Quality Management Service, 80, Seonyudong 1-ro, Youngdeungpo-gu, Seoul, Korea;

    Division of Safety Analysis, Experiment Research Institute National Agricultural Products Quality Management Service, 80, Seonyudong 1-ro, Youngdeungpo-gu, Seoul, Korea;

    Division of Safety Analysis, Experiment Research Institute National Agricultural Products Quality Management Service, 80, Seonyudong 1-ro, Youngdeungpo-gu, Seoul, Korea;

    Division of Safety Analysis, Experiment Research Institute National Agricultural Products Quality Management Service, 80, Seonyudong 1-ro, Youngdeungpo-gu, Seoul, Korea;

    Division of Safety Analysis, Experiment Research Institute National Agricultural Products Quality Management Service, 80, Seonyudong 1-ro, Youngdeungpo-gu, Seoul, Korea;

  • 会议组织
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Benzoapyrene (BaP); black ginseng; florescence detector; atmospheric pressure chemical ionization-MS/MS; polycyclic aromatic hydrocarbons(PAHs);

    机译：苯并[a] py（BaP）;黑参荧光检测器大气压化学电离-MS / MS；多环芳烃（PAHs）;

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