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Structural and Optical Properties of Strained Gallium Nitride Nanowires

机译:应变氮化镓纳米线的结构和光学性质

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摘要

Bulk-quantity single crystalline wurtzite gallium nitride nanowires with a mean diameter of 25 nm were synthesized on silicon substrate using a catalyst-assisted reaction of gallium and gallium nitride mixture with ammonia. They exhibit a strong and broad photoluminescence in the energy range of 2.9-3.6 eV with no yellow band. X-ray diffraction and Raman scattering data suggest that the nanowires would experience biaxial compressive stresses in the inward radial direction and the induced tensile uniaxial stresses in the wire axis. The blue photoluminescence would originate from the recombination of the bound excitons under the compressive and tensile stresses.
机译:利用镓和氮化镓混合物与氨的催化剂辅助反应,在硅衬底上合成了平均直径为25 nm的块状单晶纤锌矿型氮化镓纳米线。它们在2.9-3.6 eV的能量范围内显示出强而宽的光致发光,没有黄带。 X射线衍射和拉曼散射数据表明,纳米线将在向内的径向方向上经受双轴压缩应力,而在线的轴线上产生诱导的单轴拉伸应力。蓝色光致发光将源自结合的激子在压缩应力和拉伸应力下的重组。

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