Functionalization of porous silicon surfaces by solution-phase reactions with alcohols and grignard reagents

机译：通过与醇和格氏试剂的溶液相反应使多孔硅表面功能化

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This paper describes the covalent attachment of various organic molecules to the hydrogen-terminated surface of porous silicon using alcohols and Grignard reagents. With alcohols, the chemical reaction forms Si-O-C attachments to the silicon substrate and requires modest heating (40-70deg C). With Grignard reagents, the reaction proceeds at room temperature and forms a covalent film that is attached by Si-C bonds to the silicon support. Evidence for these reactions is provided by infrared and x-ray photoelectron spectroscopies.

机译：本文介绍了使用醇和格氏试剂将各种有机分子共价连接到多孔硅的氢封端表面。与醇类发生化学反应后，Si-O-C附着在硅基板上，需要适度加热（40-70℃）。使用格氏试剂，反应在室温下进行并形成共价膜，该共价膜通过Si-C键连接到硅载体上。这些反应的证据由红外和X射线光电子能谱提供。

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《Symposium on Microcrystalline and Nanocrystalline Semiconductors-1998 held November 30-December 3, 1998, Boston, Massachusetts, U.S.A.》|1998年|p.167-172|共6页
会议地点 Boston MA(US)
作者
N.Y. Kim; P.E. Laibinis;
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原文格式 PDF
正文语种 eng
中图分类无线电电子学、电信技术;
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机译：使用格氏试剂在多孔硅表面上接枝功能化聚合物
2. A Deuterium Labeling, FTIR, and Ab Initio Investigation of the Solution-Phase Thermal Reactions of Alcohols and Alkenes with Hydrogen-Terminated Silicon Surfaces [J] . J. E. Bateman, R. D. Eagling, B. R. Horrocks, The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2000,第23期

机译：氘标记，FTIR和从头开始研究醇和烯烃与氢封端的硅表面的固相热反应
3. Surface modification of porous silicon dioxides achieved using conventional solution-phase reagents under solvent-free conditions [J] . Alpay Taralp, Done Demirgoz, Helen T. Vakos, Polymer Preprints . 2003,第1期

机译：在无溶剂条件下使用常规溶液相试剂对多孔二氧化硅进行表面改性
4. Functionalization of porous silicon surfaces by solution-phase reactions with alcohols and grignard reagents [C] . N.Y. Kim, P.E. Laibinis, Materials Research Society Symposium on microcrystalline and nanocrystalline semiconductors . 1999

机译：用醇和格氏试剂溶液相反应的多孔硅表面的官能化
5. Quenching of porous silicon photoluminescence by aromatic molecules, and surface derivatization of porous silicon with dimethyl sulfoxide, aryllithium, or alkyllithium reagents [D] . Song, Jae Hee 1998

机译：芳香族分子淬灭多孔硅的光致发光，并用二甲基亚砜，芳基锂或烷基锂试剂对多孔硅进行表面衍生
6. Bioconjugate functionalization of thermally carbonized porous silicon using a radical coupling reaction [O] . Beniamino Sciacca, Sara D. Alvarez, Francesco Geobaldo, -1

机译：使用自由基偶联反应热碳化的多孔硅的生物缀合物的官能化
7. Preparation of silicon esters such as silicon tetrapropionate and their reaction with Grignard reagents to form tertiary alcohols, ketones, and silicones [O] . Moore McDonald. 1957

机译：硅酸酯（如四丙酸硅）的制备及其与格氏试剂的反应，形成叔醇，酮和硅酮
8. Patterned Functionalization of Gold and Single Crystal Silicon Via Photochemical Reaction of Surface-Confined Derivatives of (Eta5-C5H5)MN(CO)3. [R] . Kang, D., Wrighton, M. S. 1990

机译：通过（Eta5-C5H5）mN（CO）3的表面限制衍生物的光化学反应对金和单晶硅进行图案化功能化。

Functionalization of porous silicon surfaces by solution-phase reactions with alcohols and grignard reagents

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