声明
Chapter 1 Studies on corannulene and its derivatives
1.1 Introduction
1.2 Preparation of corannulene
1.3 Functionalized corannulene
1.3.1 Halogenated corannulenes
1.3.2 Other functionalized corannulene synthesized by one step
1.3.3 Substituted corannulene synthesized by multi-step
Chapter 2 The developments of new functionalization strategies of aryl amides
2.1 Background
2.2 Project design
2.3 Results and discussion
Chapter 3 Syntheses and derivatization of bromine-containing corannulenes
3.1 Background
3.2 Project design
3.3 Results and discussion
Chapter 4 Conclusion and future plan
4.1 Conclusion
4.2 Future plan
Chapter 5 Experimental section
5.1 Equipments, reagents and general notes
5.2 Synthesis of dihydroisoquinolones and corannulene derivatives
5.2.1 Synthesis of dihydroisoquinolones
5.2.2 Synthesis of substrates (monobromocorannulene and tetrabromocorannulene)
5.2.3 Synthesis of mono-substituted corannulene derivatives
5.2.4 Synthesis of tetra-substituted corannulene derivatives
5.2.5 Data of dihydroisoquinolones and corannulene derivatives
5.2.6 UV-vis spectroscopic data
参考文献
Appendix NMR Spectra of some of the representative examples in the thesis
Notes on publications and participation in scientific research
致谢
天津大学;