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Synthesis and ligand substitution in polyhedral borane anions and transition metal complexes of heteroatom borane cages.

机译：多面体硼烷阴离子和杂原子硼烷笼的过渡金属络合物中的合成和配体取代。

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everal new metallaheteroboranes have been synthesized, including one new complex of the dicarbollide nido-7,8-;The palladium-mediated substitution reaction was extended to icosahedral metallaheteroboranes. Treatment of 1,1-(;Using this substitution method, a metallaborane complex containing palladium (III) and the first doubly charge-compensated ollide ion, 1,2-Br;A potentially general method to substitute neutral for hydride ligands on borane anions, resulting in charge-compensated boranes, is demonstrated. This method uses a palladium reagent,

机译：合成了数不清的新金属杂多异戊二烯，包括一种新的双碳酰氨基7,8-复合物；钯介导的取代反应扩展到二十面体金属杂多异戊二烯。 1,1-（;;使用该取代方法处理含有钯（III）和第一个双电荷补偿的碘离子1,2-Br的金属戊烷络合物;用中性取代硼烷阴离子上的氢化物配体的潜在通用方法证明产生了电荷补偿的硼烷，该方法使用钯试剂，

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作者
Jasper, Stephen Alan, Jr.;
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作者单位

Indiana University.;

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授予单位 Indiana University.;
学科 Chemistry Inorganic.
学位 Ph.D.
年度 1995
页码 233 p.
总页数 233
原文格式 PDF
正文语种 eng
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机译：银和铜配合物-多面体硼烷，碳硼烷和金属碳硼烷阴离子的合成和X射线结构？
2. Synthesis and comparative toxicology of a series of polyhedral borane anion-substituted tetraphenyl porphyrins. [J] . Koo MS, Ozawa T, Santos RA, Journal of Medicinal Chemistry . 2007,第4期

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3. Alkali Metal and Alkaline Earth Metal Complexes with the Bis(borane-diphenylphosphanyl)amido Ligand - Synthesis, Structures, and Catalysis for Ring-Opening Polymerization of epsilon-Caprolactone [J] . Bhattacharjee Jayeeta, Das Suman, Reddy T. Dhileep N., Zeitschrift fur Anorganische und Allgemeine Chemie . 2016,第2期

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4. Synthesis of Amine-Borane Intramolecular Complexes through Palladium-Catalyzed Rearrangement of Ammonioalkynyltriarylborates [C] . Naoki Ishida, Mizuna Nanirni, Masahiro Murakami Symposium on Organometallic Chemistry . 2008

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5. Synthesis and luminescence of organometallic complexes. Part I: Rhenium(I) carbonyl complexes and their ligands in anion recognition. Part II: Chiral ferrocenyl-substituted N-heterocyclic carbene ligands [D] . Odago, Maurice Otieno 2010

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6. Synthesis of Polyhedral Borane Cluster Fused Heterocycles via Transition Metal Catalyzed B-H Activation [O] . Ke Cao, Cai-Yan Zhang, Tao-Tao Xu, 2020

机译：过渡金属催化的B-H活化合成多面体硼烷团簇稠合杂环
7. Silver and Copper Complexes with closo-Polyhedral Borane, Carborane and Metallacarborane Anions: Synthesis and X-ray Structure [O] . Varvara V. Avdeeva, Elena A. Malinina, Igor B. Sivaev, 2016

机译：具有闭合多面体硼烷，碳硼烷和金属碳硼烷阴离子的银和铜配合物：合成和X射线结构
8. Transition-Metal-Promoted Reactions of Boron Hydrides. 7. Platinum(II) Bromide Catalyzed Cage Growth and Dehydrocoupling Reactions of Diborane with Small Polyhedral Carboranes and Boranes: Synthesis of a New Arachno Carborane, 5,6-C2B6H12, and the Diborane-Coupled Compounds 2:1', 2'-(1,6-C2B4H5)(B2H5) and 2:1',2'-(B5H8)(B2H5). [R] . Corcoran, E. W., Sneddon, L. G. 1985

机译：过渡金属促进的氢化硼反应。 7.铂（II）溴化物催化的笼型生长和乙硼烷与小多面体碳硼烷和硼烷的脱氢偶联反应：合成新的arachno Carborane，5,6-C2B6H12和乙硼烷偶联化合物2：1'，2' - （ 1,6-C2B4H5）（B2H5）和2：1'，2' - （B5H8）（B2H5）。

Synthesis and ligand substitution in polyhedral borane anions and transition metal complexes of heteroatom borane cages.

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