Two complexes constructed with 2,4＇-biphenyldicarboxylic acid (2,4＇-H2bpdc),1,10-phenanthroline derivative ligands and metallic salts,namely,{[Co(2,4＇-bpdc)(L)(H2O)]· H2O}n (1),[Mn(2,4＇-bpdc)(L)(H2O)]n (2) (L=imidazo [4,5-f][1,10]phenanthroline) were synthesized under hydrothermal reaction.The complexes are characterized by elemental analysis,single crystal X-ray diffraction and thermogravimetric analysis.Complex 1 has a 1D chain structure.Complex 2 forms a one-dimensional double-chain structure.They both further linked into a three-dimensional net structure via the intermolecular hydrogen bonds and aromatic π-πr interactions.CCDC:934719,1; 934720,2.%在水热条件下,以2,4＇-联苯二羧酸(2,4＇-H2bpdc)和咪唑并[4,5-f][1,10]邻菲咯啉(L)为配体构筑了两种配合物{[Co(2,4＇-bpdc)(L)(H2O)]· H2O]n(1)和[Mn(2,4＇-bpdc)(L)(H2O)]n(2),并利用元素分析、X-射线单晶衍射和热重分析对其结构进行了表征.配合物1具有一维链状结构,配合物2展示了一维双链结构,两个配合物都通过分子间氢键和π-π相互作用形成三维网状结构.
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