通过水热法合成了一个新的金属-有机配位聚合物[Zn(pzdc)(bix)0.5(H2O)]n(1)(H2pzdc=吡嗪-2,3-二甲酸,bix=1,4-双(咪唑基1-甲基)-苯).并对其进行了元素分析、红外光谱、紫外光谱和X-射线单晶衍射测定.该配合物属于三斜晶系,P(1)空间群.晶体学数据:a=0.737 27(8),b=1.004 45(12),c=1.079 10(13) nm,α=113.771(2),β=102.005(2),γ=93.586(2)°,V=0.705 71(14) nm3,C13H11N4O5Zn,Mr=368.63,Dc=1.735 g·cm-3,μ(Mo Kα)=1.773 mm-1,F(000)=374,Z=2,最终R=0.027 6,wR=0.067 7用于2 460个可观测点.在晶体结构中,锌离子通过吡嗪-2,3-二甲酸和1,4-双(咪唑基1-甲基)-苯)配体桥联成二维层状结构.而且该配合物通过氢键和π-π堆积作用扩展成三维超分子网状结构.此外还研究了它的荧光性质.%A new metal-organic coordination polymer [Zn(pzdc)(bix)0.5(H2O)]n (1) (H2pzdc=pyrazine-2,3-dicarboxylic acid,bix=1,4-bis(imidazol-1-ylmethyl)-benzene) has been hydrothermally synthesized and structurally characterized by elemental analysis,IR spectrum,UV spectrum and single-crystal X-ray diffraction.The complex crystallizes in triclinic,space group P(1) with a=0.737 27(8),b=1.004 45(12),c=1.079 10(13) nm,α=113.771(2),β=102.005(2),γ=93.586(2)°,V=0.705 71(14) nm3,C13H11N4O5Zn,Mr=368.63,Dc=1.735 g·cm-3,μ(Mo Kα)=1.773 mm-1,F(000)=374,Z=2,the final R =0.027 6 and wR =0.067 7 for 2 460 observed reflections (Ⅰ＞2σ (Ⅰ)).In the crystal structure,1 shows a two-dimensional layer structure bridged by pzdc and bix ligands.Furthermore,it exhibits a 3D supramolecular network through hydrogen bonding and π-π stacking interactions.Moreover,its luminesent property has been investigated in the solid state.CCDC:878878.
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