A nickel(Ⅱ) complex[Ni(L)(Mf)]n with 2-hydroxyacetophenone salicyloylhydrazone(H2L) and monodentate N-donor heterocycle,morpholine (Mf) has been synthesized and characterized by elemental analysis,UV,TG and X-Ray diffraction.In the complex,the Ni(Ⅱ) ion is in a square-planar N2O2 coordination geometry formed by the phenolate-O,the imine-N and the deprotonated amide-O atoms from L2-,and the N atom of neutral morpholine.In intermolecular hydrogen bonds.The electrochemical property was studied with an electrochemical analyzer.%合成了1个含2-羟基苯乙酮缩水杨酰腙(H2L)和单齿N-杂环分子吗啡啉(Mf)的镍(Ⅱ)配合物[Ni(L)(Mf)]n,并通过元素分析、紫外光谱、热分析以及单晶衍射等手段进行表征.在配合物中.中心Ni(Ⅱ)与酰腙配体的酚氧、亚胺氮、去质子酰胺氧原子以及中性吗啡氮原子配位形成平面四方形的N2O2配位构型.配合物通过N-H(吗啡)…O(吗啡)分子间氢键作用构筑成一维超分子网络结构.采用循环伏安法研究了化合物的电化学性质.
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