首页> 中文期刊> 《无机化学学报》 >配合物Cu2(phen)2(SiW12O40)(H2O)7的合成、晶体结构及电化学分析

配合物Cu2(phen)2(SiW12O40)(H2O)7的合成、晶体结构及电化学分析

         

摘要

The title complex has been synthesized by the reaction of silicotungstic acid, 1,10-phenanthroline(phen) monohydrate and cupric acetate. The crystal structure belongs to triclinic system, space group P-1 with a=1.15846(15) nm, b=1.658 8(2) nm, c=1.6644(2) nm, α=82.090(2)°,β=76.001(2)°, γ=86.531(2)°, and V=3.072 6(7)is coordinated with two nitrogen atoms from the one phen and three oxgygen atoms from three water, forming a distorted square-pyramid configuration The cyclic voltametric behavior of the complex is also reported. CCDC:298807.

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