Five coordination complexes,formulated as {[Zn(btbb)0.5(m-phda)] ·0.5H2O}n (1),{[Cd2(btbb)(adtda)2(H2O)]· H2O}n (2),[Mn2(btbb)(tbi)2]n (3),{[Cd(btbb)05(3-Nitro-o-bdc)(H2O)]· H2O}n (4) and [Cd2(btbb)(tbi)2]n (5) (btbb=1,4-bis (2-(4-thiazolyl)benzimidazole-1-ylmethyl)benzene,m-H2phda =m-phenylenediacetic acid,H2adtda =1,3-adaman-tanedicarboxylic acid,H2tbi=5-tert-butylisophthalic acid,3-Nitro-o-H2bdc=3-Nitro-1,2-benzenedicarboxylic acid),have been obtained by hydro(solv)thermal reactions and structurally characterized.Complex 1 exhibits a 1D chain structure containing 22-membered rings.Complex 2 features a 1D chain structure having an 8-membered rings and btbb serves only as an ornament here.Complex 3 is a 1D double chain structure.Complex 4 possesses a 1D chain structure containing 14-membered rings.Complex 5 shows a 1D double chain taking on stair-step.CCDC:1883643,1;1883644,2;1883645,3;1883646,4;1883647,5.%通过水热或溶剂热合成的方法制备了5个一维配合物{[Zn(btbb)0.5(m-phda)]·0.5H2O}n(1),{[Cd2(btbb) (adtda)2(H2O)]·H2O}n(2),[Mn2(btbb)(tbi)2]n(3),{[Cd(btbb)0.5(3-Nitro-o-bdc)(H2O)]·H2O}n(4)和[Cd2(btbb)(tbi)2]n(5)(btbb=1,4-双(2-(4-噻唑基)苯并咪唑-1-基甲基)苯,m-H2phda=间苯二甲酸,H2adtda=1,3-金刚烷二羧酸,H2tbi=5-叔丁基间苯二甲酸,3-Nitro-o-H2bdc=3-硝基-1,2-苯二甲酸).配合物1是一个包含22元环的一维链.配合物2是一个包含8元环的一维链,并且氮配体在这个一维链中仅仅起到装饰作用.配合物3是一个一维双链结构.配合物4是一个包含14元环的一维链.配合物5是一个阶梯状的一维双链结构.
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