合成了β-二酮合钴(Ⅱ)、镍(Ⅱ)、铜(Ⅱ)棒状金属有机液晶,并对其介晶性进行了表征.研究表明,所有目标配合物都具有液晶性,其中,配合物3,6在熔点附近产生分解现象.%Rod-like organometallic liquid crystals with β-diketonate cobalt ( Ⅱ ),nickel( Ⅱ ) and copper( Ⅱ ) complexes were synthesized and characterized. The results show that all the complexes have liquid-crystal properties, but 3, 6 complexes haven't shown clearing point temperature because of the decomposition at melting point.
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