利用双三丁基氧化锡与2,5-吡啶二羧酸反应,合成了新的有机锡化合物[(nBu3Sn)2(2,5-pdc)]∞(pdc=吡啶二羧酸),并用元素分析、红外光谱、核磁共振氢谱和X-射线单晶衍射对该化合物进行了表征.结果表明,该化合物为二维网状结构.%A new organotin heterocyclicdicarboxylate [(nBu3Sn)2(2,5-pdc)]∞ was synthesized by the reaction of [(nBu)3Sn]2 O with 2,5- pyridinedicarboxylate.Complexe has been characterized by elemental,IR,1H NMR analyses and X-ray crystallographic diffraction analyses.This complex has a 2D network structure.
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