合成了两种含 POSS 的金属铱（Ir）配合物磷光材料 POSS‐7Cz‐Ir（L）2（q）（POSS‐1）和 POSS‐6Cz‐2Ir（L）2（q）（POSS‐2）。用1 HNMR、FT‐IR和MS对配体和磷光材料的结构进行了表征，并分别测定了两种磷光材料的紫外‐可见吸收光谱及光致发射光谱，通过热重和X RD分析了其稳定性。%Two new phosphorescent iridium(Ir) complexes containing polyhedral oligomeric silsesquioxane (POSS) core , such as POSS‐7Cz‐Ir (L )2 (q ) (POSS‐1 ) and POSS‐6Cz‐2Ir (L )2 (q ) (POSS‐2 ) , are synthesized and characterized by 1 HNMR , FT‐IR and MS . Their UV‐vis absorption and photoluminescence spectra are investigated . The thermal stability and morphology of POSS‐1 and POSS‐2 are also investigated by TG and XRD analysis .
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