以对苯二甲酰氯与罗丹明B乙二胺缩合反应的产物(Rh-1)为荧光“关-开”型探针,研究了探针Rh-1选择性识别 Fe3+的各种影响因素,建立了Rh-1荧光检测分析痕量Fe3+的方法,其线性范围为1.0×10-7 mol/L~2.6×10-5 mol/L,检出限为2.31×10-8 mol/L。%A turn-on fluorescent probe Rh -1 based on rhodamine for trivalent ferric ion ( Fe3+) was synthesized .It was studied that the various factors affected the fluorescence of Rh -1 and Fe3+complex.And an approach was developed for the detection of trace amount of Fe 3+based on Rh-1 as fluorescent probe .The linear range covered from 1.0 ×10 -7 mol/L to 2.6 ×10 -5 mol/L, and the detection limit was found to be 2.31 ×10 -8 mol/L.
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