利用水热反应合成了聚5,6-二氧代-1,10-邻菲咯啉配合物晶体.同时利用X射线单晶衍射对标题化合物进行了表征.晶体数据:单斜晶系,空间群P2(1)/c,a=1.7365 (4) nm,b=1.0961 (2)nm,c=1.4424nm,β=111.75(3)°,V=2.5501(9)nm3,Dc=1.470mg/m3,Z=4,F(000) =1168,最终残差因子R1 =0.0445,wR2=0.1053,对于全部数据R1=0.0915,wR2=0.1198.%a Two-Polymerization of 5,6-dioxo-1,10-Phenanthroline monohydrate Coordination Polymer has been synthesized through hydrothermal reaction and structurally characterized by single crystal X-ray diffraction method.In addition,the results of IR and 1 H NMR analysis were presented.Crystal data:tetragonal,space group P2 (1)/c,a =1.7365 (4) nm,b =1.0961 (2) nm,c =1.4424nm,β =111.75 (3) °,V =2.5501 (9) nm3,Dc =1.470mg/m3,Z =4,F(000) =1168 final R indices [I ＞2sigma(I)] R1 =0.0445,wR2 =0.1053,for all reflections R1 =0.0915,wR2 =0.1198.
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