APPLICATION OF 129I MOSSBAUER EFFECT TO BIOLOGICAL SYSTEMS: STUDIES WITH HEME MODELS

机译：129I MOSSBAUER效应在生物系统中的应用：血红素模型研究

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The Mossbauer effect associated with ¹²⁹I, ¹²⁵Te, and ⁵⁷Fe has been applied to investigate structural properties of the axial ligands in ferric-high spin hematoheme-I, hematoheme-Te, and hematoheme-histidine-iodide. The magnitude and sign of the ¹²⁹I quadrupole coupling constant (e²qQ) and the isomer shift, as deduced from the Mossbauer effect spectra, are consistent with an axial, s-p hybridized bond of overwhelming σ-character. Identical coupling constant (e²qQ(¹²⁷I) = -1826 ± 3 MHz) were measured for both heme-I and hematoheme-histidine-iodide. Implications of this result to the nature of ferric-high spin heme-histidine complexing are discussed. A stable heme ¹²⁵Te species formed in the electron-capture decay of heme-¹²⁵I is observed, and structural properties of this singly bonded telluride ligand are discussed.

机译：^{129 I，^{125 Te和^{57 Fe的Mossbauer效应已被用于研究高铁离子中轴向配体的结构性质旋转血红素-I，血红素-Te和血红素-组氨酸-碘。由Mossbauer效应谱推导的^{129 I四极偶合常数（e ^{2 qQ）的大小和正负号以及异构体位移与轴向sp压倒性的σ字符的杂化键。测定血红素I和血红素-组氨酸碘的相同的耦合常数（e ^{2 qQ（^{127 I）= -1826±3 MHz）。讨论了该结果对高铁自旋血红素-组氨酸配合物的性质的影响。观察到在血红素-^{125 I的电子捕获衰变中形成的稳定的血红素^{125 Te物种，并讨论了这种单键碲化物配体的结构性质。}}}}}}}}}

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期刊名称 Proceedings of the National Academy of Sciences of the United States of America
作者
M. Pasternak; Peter G. Debrunner; G. DePasquali; Lowell P. Hager; L. Yeoman;
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年(卷),期 1970(66),4
年度 1970
页码 1142–1149
总页数 8
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专利

1. Iron(II) carboxylate complexes based on a tetraimidazole ligand as models of the photosynthetic non-heme ferrous sites: Synthesis, crystal structure, and Mossbauer and magnetic studies [J] . Lemercier G., Mulliez E., Brouca-Cabarrecq C., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2004,第6期

机译：基于四咪唑配体的羧酸铁（II）配合物，作为光合非血红素亚铁位点的模型：合成，晶体结构以及Mossbauer和磁性研究
2. Iron(ll) Carboxylate Complexes Based on a Tetraimidazole Ligand as Models of the Photosynthetic Non-Heme Ferrous Sites:Synthesis,Crystal Structure,and Mossbauer and Magnetic Studies [J] . Gilles Lemercier, Etienne Mulliez, Chantal Brouca-Cabarrecq, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2004,第6期

机译：基于四咪唑配体的铁（II）羧酸盐配合物作为光合非血红素亚铁位点的模型：合成，晶体结构以及Mossbauer和磁学研究
3. CHEMILUMINESCENCE AND EPR STUDIES ON THE EXCITATION SITE OF FERRIC-HEME-OXO COMPLEXES OF NATURAL AND MODEL HEME SYSTEMS [J] . Liu Y., Nohl H. Photochemistry and Photobiology: An International Journal . 1995,第3期

机译：天然和模型血红素系统的铁-血红素-氧配合物激发部位的化学发光和EPR研究
4. Study of Magnetic Materials by Mossbauer Thermal Scans. Application to Nanocrystalline Systems [C] . F. H. Sanchez, G. A. Pasquevich, P. Mendoza Zelis Workshop on Metastable and Nanostructured Materials . 2004

机译：Mossbauer热扫描研究磁性材料。在纳米晶体系统中的应用
5. SPECTROSCOPIC AND THERMODYNAMIC STUDIES OF MODEL SYSTEMS FOR HEME, HEME-COPPER, AND COPPER-CONTAINING ENZYMES [D] . STONG, JOHN D., III. 1977

机译：血红素，血红素铜和含铜酶模型系统的光谱学和热力学研究
6. Review of stochastic hybrid systems with applications in biological systems modeling and analysis [O] . Xiangfang Li, Oluwaseyi Omotere, Lijun Qian, 2017

机译：综述随机混合系统及其在生物系统建模和分析中的应用
7. APPLICATION OF 129I MOSSBAUER EFFECT TO BIOLOGICAL SYSTEMS: STUDIES WITH HEME MODELS* [O] . Pasternak, M., Debrunner, Peter G., DePasquali, G., 1970

机译：129I MOSSBAUER效应在生物系统中的应用：血红素模型研究*

APPLICATION OF 129I MOSSBAUER EFFECT TO BIOLOGICAL SYSTEMS: STUDIES WITH HEME MODELS

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