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Enantioselective Rhodium‐Catalyzed Coupling of Arylboronic Acids 13‐Enynes and Imines by Alkenyl‐to‐Allyl 14‐Rhodium(I) Migration

机译：烯基至烯丙基14-铑（I）迁移对芳基硼酸13-烯炔和亚胺的对映选择性铑催化偶联

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摘要

A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1,3‐enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl‐to‐allyl 1,4‐rhodium(I) migration.

机译：手性铑配合物催化芳基硼酸，1,3-烯炔和亚胺的高度对映选择性偶联，生成均烯丙基氨基磺酸盐。关键步骤是烯基至烯丙基1,4-铑（I）的迁移产生烯丙基铑（I）物种。

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期刊名称 Wiley-Blackwell Online Open
作者
Michael Callingham; Dr. Benjamin M. Partridge; Dr. William Lewis; Prof. Hon Wai Lam;
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作者单位

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年(卷),期 -1(56),51
年度 -1
页码 16352–16356
总页数 5
原文格式 PDF
正文语种
中图分类
关键词
allylation asymmetric catalysis imines isomerization rhodium;

机译：烯丙基化;不对称催化;亚胺;异构化;铑;

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专利

1. Enantioselective Rhodium-Catalyzed Coupling of Arylboronic Acids, 1,3-Enynes, and Imines by Alkenyl-to-Allyl 1,4-Rhodium(I) Migration [J] . Michael Callingham, Benjamin M. Partridge, William Lewis Angewandte Chemie . 2017,第51期

机译：通过链烯基 - 烯丙基1,4-铑（I）迁移致注重芳基硼酸，1,3-烯醇和亚胺的铑铑催化偶联偶联
2. Highly enantioselective rhodium-catalyzed cross-coupling of boronic acids and racemic allyl halides [J] . Gonzalez Jesus, van Dijk Lucy, Goetzke F. Wieland, Nature protocols erecipes for researchers . 2019,第10期

机译：高度对辅助的铑催化的硼酸和外消旋烯丙基卤化物的交叉偶联
3. Enantioselective Reductive Coupling of 1,3-Enynes to Heterocyclic Aromatic Aldehydes and Ketones via Rhodium-Catalyzed Asymmetric Hydrogenation:Mechanistic Insight into the Role of Bronsted Acid Additives [J] . Venukrishnan Komanduri, Michael J.Krische Journal of the American Chemical Society . 2006,第51期

机译：铑催化的不对称加氢反应使1,3-烯炔与杂环芳族醛和酮的对映选择性还原偶联：对布朗斯台德酸添加剂作用的机理研究
4. Enantioselective addition of arylboronic acids to aldimines catalyzed by rhodium-bispnosphoramidide complex [C] . Kazunori Kurihara, Yoshinori Takahashi, Yasunori Yamamoto Symposium on Organometallic Chemistry . 2008

机译：通过铑 - 双磷酰胺复合物催化的芳基硼酸向醛氨酰亚胺的映选择性添加
5. Enantioselective rhodium-catalyzed [2+2+2] and [4+2+2] cycloaddition reactions of alkenyl heterocumulenes: Applications to alkaloid synthesis [D] . Yu, Robert Tzu Hsiang 2009

机译：对映体选择性铑催化的烯基杂枯烯的[2 + 2 + 2]和[4 + 2 + 2]环加成反应：在生物碱合成中的应用
6. Arylative Intramolecular Allylation of Ketones with 13‐Enynes Enabled by Catalytic Alkenyl‐to‐Allyl 14‐Rhodium(I) Migration [O] . Dr. Benjamin M. Partridge, Michael Callingham, Dr. William Lewis, -1

机译：催化烯基到烯丙基14-铑（I）迁移使酮与13-烯炔的分子内烯丙基化
7. Enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and Imines by alkenyl-to-allyl 1,4-rhodium(I) migration [O] . Callingham, Michael, Partridge, Benjamin M., Lewis, William, 2017

机译：烯基到烯丙基的1,4-铑（I）的迁移，对映体铑催化的芳基硼酸，1,3-烯炔和亚胺的偶联

Enantioselective Rhodium‐Catalyzed Coupling of Arylboronic Acids 13‐Enynes and Imines by Alkenyl‐to‐Allyl 14‐Rhodium(I) Migration

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