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Benefits, Problems, and Solutions of Silver Nanowire Transparent Conductive Electrodes in Indium Tin Oxide (ITO)-Free Flexible Solar Cells

机译:银纳米线透明导电电极在氧化铟锡(ITO) - 免费柔性太阳能电池中的益处,问题和解决方案

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摘要

In this review, silver nanowires (AgNWs) are introduced, as the primary material to replace indium tin oxide for fabricating cost-effective flexible organic solar cells (FOSCs), because of their remarkable solution-processing, flexibility, transparency, and conductivity, along with their enhanced properties in terms of light-scattering, plasmonic effects, and transmittance in the near infrared region. The drawbacks of AgNWs, particularly their high roughness, low adhesion to substrates, atmospheric corrosion, degradation under UV and visible light, and poor contact at wire-wire junctions, must be resolved prior to their use in commercial FOSCs applications. Herein, comparisons among all candidates (e.g., graphene, carbon nanotubes, metal grids, and conducting polymers), along with a report of all recent progress in addressing these issues for using AgNWs as flexible transparent conductive electrodes (TCEs), are discussed. In addition, recent publications on the fabrication of highly efficient FOSCs based on AgNWs are summarized. The discussed issues regarding AgNWs-TCEs apply not only to FOSCs, but can be generalized for other third-generation solar cells, such as perovskite solar cells and dye-sensitized solar cells; additionally, they provide insight for other optoelectronic applications, such as organic light-emitting diodes, liquid crystal displays, smart windows, touch panels, and heaters.
机译:在该综述中,引入银纳米线(AGNW)作为替代氧化铟锡的主要材料,以制造成本有效的柔性有机太阳能电池(FOSC),因为它们具有显着的解决方案 - 加工,灵活性,透明度和电导率在近红外区域的光散射,等离子体效应和透射率方面具有增强的性质。 AgNW的缺点,特别是它们的高粗糙度,低粘附性对底物,大气腐蚀,降解,在IV和可见光下,在线连接的差的接触,在商业FOSC应用之前必须解决。在此,讨论了所有候选者(例如,石墨烯,碳纳米管,金属网格和导电聚合物)的比较,以及解决这些问题的所有最近进展的报告,用于使用AGNW作为柔性透明导电电极(TCS)。此外,总结了基于AGNW的高效FOSCS制造的最近出版物。讨论的关于AGNWS-TCCS的问题不仅适用于FOSC,而是可以推广其他第三代太阳能电池,例如Perovskite太阳能电池和染料敏化太阳能电池;此外,它们提供了对其他光电应用的洞察力,例如有机发光二极管,液晶显示器,智能窗口,触摸板和加热器。

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