Comparative study on the photocatalytic mineralization of homologous aliphatic acids and alcohols

Arana J; Rodriguez JMD; Diaz OG; Melian JAH; Pena JP

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Comparative study on the photocatalytic mineralization of homologous aliphatic acids and alcohols

机译：同源脂肪酸和醇类光催化矿化的比较研究

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The photocatalytic mineralization of methanol, ethanol and I-propanol is compared with those of their homologous carboxylic acids (formic, acetic and propanoic). The presence of S2O82- ions almost does not affect the alcohols mineralization. But, those of the acids are slowed down. In addition to this, adding H2O2 inhibits the alcohols mineralization and those of the acids, but to a lesser extent.

机译：将甲醇，乙醇和异丙醇的光催化矿化与其同源羧酸（甲酸，乙酸和丙酸）进行了比较。 S 2 O 82-离子的存在几乎不影响醇的矿化。但是，这些酸的速度变慢了。除此之外，添加H2O2可以抑制醇类和酸类的矿化，但程度较小。

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来源
《Applied Surface Science》 |2006年第23期|p. 8193-8202|共10页
作者
Arana J; Rodriguez JMD; Diaz OG; Melian JAH; Pena JP;
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作者单位

CSIC, Inst Ciencia Mat, Grp FEAM, E-41080 Seville, Spain;

Univ Las Palmas Gran Canaria, CIDIA, Dept Quim, E-35017 Las Palmas Gran Canaria, Spain;

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原文格式 PDF
正文语种 eng
中图分类应用物理学;
关键词
photocatalysis; alcohols; carboxylic acids; photoactive centres; FT-IR; HYDROXYLATED TIO2 SURFACES; POLYCRYSTALLINE TIO2; TITANIUM-DIOXIDE; PHOTO-ADSORPTION; DEGRADATION; WATER; OXIDATION; RUTILE; OXYGEN; FTIR;

机译：光催化;醇;羧酸;光活性中心;FT-IR;羟基氧化TIO2表面;TiO2结晶;二氧化钛;光吸附;降解;废水;氧化;橡胶;氧气;FTIR;

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专利

1. Studies in detoxication. 46. The metabolism of aliphatic alcohols. The glucuronic acid conjugation of acyclic aliphatic alcohols [J] . I. A. Kamil, J. N. Smith, R. T. Williams The biochemical journal . 1953,第1期

机译：解毒研究。 46.脂肪醇的代谢。无环脂肪醇的葡萄糖醛酸共轭
2. Photocatalytic Decomposition of Aliphatic Alcohols,Acids,and Esters [J] . M.Catherine Blount, Jason A.Buchholz, John L.Falconer Journal of Catalysis . 2001,第2期

机译：脂肪醇，酸和酯的光催化分解
3. Trace-Level Extraction Behavior of Actinide Elements by Aliphatic Alcohol Extractants in Mineral Acids: Insights into the Trace Solution Chemistry of Protactinium [J] . Knight Andrew W., Eitrheim Eric S., Nelson Andrew W., Solvent Extraction and Ion Exchange . 2016,第5a7期

机译：脂肪族醇萃取剂在无机酸中痕量Elements系元素的萃取行为：t的痕量溶液化学的见解
4. Comparison Study of Photocatalytic Activity of Titanium-Rich Materials Derived from Natural Minerals Ores Using Acidic Leaching [C] . Thanaphon Kansaard, Weerachon Phoohinkong, Wanichaya Mekprasart International Conference on Materials Science and Technology . 2017

机译：使用酸性浸出，富含天然矿物质矿石的光催化活性的比较研究
5. Synthesis gas conversion to aliphatic alcohols: Study of MoS 2 catalytic systems. [D] . Baksh, Faisal. 2010

机译：合成气向脂肪醇的转化：MoS 2催化体系的研究。
6. Studies in detoxication. 46. The metabolism of aliphatic alcohols. The glucuronic acid conjugation of acyclic aliphatic alcohols [O] . I. A. Kamil, J. N. Smith, R. T. Williams 1953

机译：解毒研究。 46.脂肪醇的代谢。无环脂肪醇的葡糖醛酸共轭
7. XXI.—Molecular rotatory power in normal homologous series. Part I. Optically active derivatives of the higher aliphatic alcohols and acids [O] . Thomas Percy Hilditch 1912

机译：XXI。 - 正常同源系列中的分子旋转功率。第一部分。高级脂族醇和酸的光学活性衍生物
8. Photocatalytic Oxidation of Multifunctional Organic Molecules. The Effect of anIntramolecular Aryl Thioether Group on the Semiconductor-Mediated Oxidation/Dehydrogenation of a Primary Aliphatic Alcohol [R] . Fox, M. A., Abdel-Wahab, A. A. 1990

机译：多功能有机分子的光催化氧化。非分子芳基硫醚基团对半导体介导的伯脂肪醇氧化/脱氢的影响

Comparative study on the photocatalytic mineralization of homologous aliphatic acids and alcohols

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