Effects of Aspartic Acid and Lysine on Thermodynamic Functions of SDS Micellization

Tianqing Liu; Jiajia Li

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Effects of Aspartic Acid and Lysine on Thermodynamic Functions of SDS Micellization

机译：天冬氨酸和赖氨酸对SDS胶束热力学功能的影响

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Aspartic acid and lysine can promote SDS micellization. The critical micellar concentration of SDS decreases with amino acid concentration, but first does and then increases with temperature. In SDS micellization, the change of standard Gibbs free energy is negative in SDS/H₂O system with or without amino acid. With the increase of amino acid concentration, the changes of mole standard Gibbs free energy and enthalpy decrease, but the change of the system's entropy increases. The effect of lysine is more than that of aspartic acid on the thermodynamic functions.

机译：天冬氨酸和赖氨酸可以促进SDS胶束化。 SDS的临界胶束浓度随氨基酸浓度而降低，但先升高后随温度升高。在SDS胶束化过程中，含或不含氨基酸的SDS / H _{2 O系统中标准Gibbs自由能的变化均为负。随着氨基酸浓度的增加，摩尔标准吉布斯自由能和焓的变化减少，但系统的熵变增加。在热力学功能上，赖氨酸的作用比天冬氨酸的作用大。}

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《Chinese Journal of Chemistry》 |2010年第11期|p.2162-2166|共5页
作者
Tianqing Liu; Jiajia Li;
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正文语种 eng
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关键词
micellization; thermodynamic function; sodium dodecyl sulfate; amino acids;

机译：胶束化;热力学功能;十二烷基硫酸钠;氨基酸;

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1. Effects of Aspartic Acid and Lysine on Thermodynamic Functions of SDS Micellization [J] . Liu,Tianqing, Li,Jiajia 中国化学（英文版） . 2010,第011期
2. Effects of substitutions of lysine and aspartic acid for asparagine at beta 108 and of tryptophan for valine at alpha 96 on the structural and functional properties of human normal adult hemoglobin: roles of alpha 1 beta 1 and alpha 1 beta 2 subunit [J] . Tsai CH, Shen TJ, Ho NT, Biochemistry . 1999,第27期

机译：赖氨酸和天冬氨酸在β108处被天冬酰胺取代和色氨酸在α96处被缬氨酸取代对人正常成人血红蛋白的结构和功能特性的影响：α1β1和α1β2亚基的作用
3. Effects of side chain length and degree of counterion binding on micellization of sodium salts of alpha-myristic acid alkyl esters in water: A thermodynamic study [J] . Okano T., Nakano TY., Ueda SI., Langmuir: The ACS Journal of Surfaces and Colloids . 2000,第8期

机译：侧链长度和抗衡离子结合程度对水中α-肉豆蔻酸烷基酯钠盐胶束化的影响：热力学研究
4. Synthesis and Characterization of Poly(L-lysine-co-L-aspartic acid) [C] . HU Yuanjun, GONG Feirong, ZHAO Yanchao, East-Asian Polymer Conference; 20060528-31; Tianjin(CN) . 2006

机译：聚（L-赖氨酸-co-L-天冬氨酸）的合成与表征
5. Effects of amino acid substitutions in and around the arginine-glycine-aspartic acid (RGD) sequence on fertilization and parthenogenetic development in mature bovine oocytes. [D] . Sessions, Benjamin R. 2004

机译：精氨酸-甘氨酸-天冬氨酸（RGD）序列内和周围的氨基酸取代对成熟牛卵母细胞受精和孤雌发育的影响。
6. Nanoliposomes of L-lysine-conjugated poly(aspartic acid) Increase the Generation and Function of Bone Marrow-derived Dendritic Cells [O] . Sun-A Im, Ki-Hyang Kim, Hong-Geun Ji, 2011

机译：L-赖氨酸结合的聚天冬氨酸的纳米脂质体增加了骨髓来源的树突状细胞的生成和功能
7. Nanoliposomes of L-lysine-conjugated poly(aspartic acid) Increase the Generation and Function of Bone Marrow-derived Dendritic Cells [O] . Im, Sun-A, Kim, Ki-Hyang, Ji, Hong-Geun, 2011

机译：L-赖氨酸结合的聚天冬氨酸的纳米脂质体增加了骨髓来源的树突状细胞的生成和功能
8. Properties of a Recombinant Human Hemoglobin with Aspartic Acid 99(beta), anImportant Intersubunit Contact Site, Substituted by Lysine [R] . Yanase, H., Cahill, S., DeLlano, J. J., 1994

机译：具有天冬氨酸99（beta）的重组人血红蛋白的性质，一种由赖氨酸取代的重要亚基间接触位点

Effects of Aspartic Acid and Lysine on Thermodynamic Functions of SDS Micellization

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