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Recent advances in supramolecular and biological aspects of arene ruthenium(Ⅱ) complexes

机译:芳烃钌(Ⅱ)配合物的超分子和生物学研究进展

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摘要

Since the synthesis of the first arene ruthenium complexes in 1967, various groups have systematically investigated the chemistry of this family of complexes because of their appealing structural diversity, related to the ways in which the arene ligand can be functionalized, their role as versatile stereochemical controlling elements in areas such as catalysis, chemical and photochemical sensing, biology and supramolecular chemistry, and their potential as metalloligands. This review is focused on the recent developments of arene ruthenium complexes towards both supramolecular chemistry and biology. Arene ruthenium complexes can form various supramolecular structures with applications as chemical/photochemical sensors, in medicine and for drug transport inside the cell. Recent developments in the chemistry of arene ruthenium complexes will likely give access to a variety of metal-based drugs/sensors within the next few years.
机译:自1967年合成第一批芳烃钌络合物以来,由于其具有吸引力的结构多样性,与芳烃配体的功能化方式有关,它们作为通用的立体化学控制作用,各个小组已系统地研究了该络合物家族的化学性质。催化,化学和光化学传感,生物学和超分子化学等领域的元素及其作为金属配体的潜力。这篇综述的重点是芳族钌配合物在超分子化学和生物学领域的最新发展。芳烃钌络合物可以形成各种超分子结构,并可以用作化学/光化学传感器,药物以及细胞内药物的转运。芳烃钌配合物化学的最新进展将可能在未来几年内使用多种金属基药物/传感器。

著录项

  • 来源
    《Coordination chemistry reviews》 |2014年第7期|31-56|共26页
  • 作者单位

    National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563 8577, Japan;

    Department of Chemistry, Faculty of Science, Banaras Hindu University, Varanasi, U.P. 221 005, India;

    National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563 8577, Japan;

    Laboratoire de Chimie de Coordination, Institut de Chimie (UMR 7177 CNRS), Universite de Strasbourg, 4 rue Blaise Pascal, 67081 Strasbourg Cedex, France;

  • 收录信息 美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Arene ruthenium; Metal coordination; Supramolecular; Biology; Drug transport; Sensors;

    机译:亚芳基钌;金属配合;超分子生物学;毒品运输;感测器;

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