Perfluoroarylgold complexes

Eduardo J. Fernandez; Antonio Laguna; M. Elena Olmos

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Perfluoroarylgold complexes

机译：全氟芳基金络合物

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The number of arylgold complexes has increased considerably, thanks to the use of perfluoroaryl groups, which confer the compounds a higher thermodynamic and kinetic stability. The present review covers the evolution of the knowledge on perfluoroarylgold chemistry since 1994. It focuses not only on the synthesis and structures, but also on the possible applications, such as those derived from the optical properties. Particular attention has been devoted to homo- or hetero-nuclear compounds displaying intra- or intermolecular metal-metal interactions. The complexes cited in this review are organized attending to the non-aryl ligand/s bonded to gold, going from the simplest ones (halides) to the non-classic ferrocene derivatives or metalloligands.

机译：由于使用了全氟芳基，芳基金配合物的数量已大大增加，这使化合物具有更高的热力学和动力学稳定性。本综述涵盖自1994年以来全氟芳基金化学知识的发展。它不仅着重于合成和结构，还着重于可能的应用，例如源自光学性质的应用。特别关注显示分子内或分子间金属-金属相互作用的同核或杂核化合物。这篇综述中引用的配合物的组织涉及与金结合的非芳基配体，从最简单的（卤化物）到非经典的二茂铁衍生物或金属配体。

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来源
《Coordination chemistry reviews》 |2008年第17期|p.1630-1667|共38页
作者
Eduardo J. Fernandez; Antonio Laguna; M. Elena Olmos;
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作者单位

Departamento de Quimica, Universidad de la Rioja, Grupo de Slntesis Quimica de La Rioja, UA-CSIC, Complejo Cientifico Tecnologico 26001 Logrono, Spain;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
gold; perfluoroaryl; metal-metal interactions; luminescence;

机译：金;全氟芳基;金属-金属相互作用;发光;

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Perfluoroarylgold complexes

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