Half-open metallocenes with heterodienyl ligands and related compounds

M. Angeles Paz-Sandoval; Irma Idalia Rangel-Salas

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Half-open metallocenes with heterodienyl ligands and related compounds

机译：具有杂二烯基配体的半开金属茂及其相关化合物

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This review surveys the chemistry of half-open metallocenes, half-sandwich and related compounds which include in their structure heterodienyl ligands, including oxygen, nitrogen, sulfur and phosphorus as heteroatoms. It covers the chemistry of the corresponding heterodienyls as anions, with main group, transition metals and the study of their reactivity; also some related compounds which contain heteroallyls, heterodiene or heterodienyl ligands are included.

机译：这篇综述综述了半开放茂金属，半三明治和相关化合物的化学结构，这些化合物的结构中包括杂二烯基配体，包括氧，氮，硫和磷作为杂原子。它涵盖了相应的杂二烯基作为阴离子的化学，主要基团，过渡金属及其反应性的研究；还包括一些含有杂烯丙基，杂二烯或杂二烯基配体的相关化合物。

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来源
《Coordination chemistry reviews》 |2006年第10期|p.1071-1106|共36页
作者
M. Angeles Paz-Sandoval; Irma Idalia Rangel-Salas;
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作者单位

Departamento de Quimica, Cinvestav, Av. IPN #2508 Col. San Pedro Zacatenco, C.P. 07360, Mexico, D.F., Mexico;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
half-open metallocenes; heterodienyl ligands; oxopentadienyl; azapentadienyl; thiapentadienyl; phosphapentadienyl;

机译：半开放茂金属;异二烯基配体;氧戊二烯基;氮杂戊二烯基;噻戊二烯基;磷戊二烯基;

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专利

1. Palladium(II) and Platinum(II) compounds of 1,1′-bis(phosphino) metallocene (m = fe, ru) ligands with metal-metal interactions [J] . Gramigna K.M., Oria J.V., Mandell C.L., Organometallics . 2013,第20期

机译：1,1'-双（膦）茂金属（m = fe，ru）配体的钯（II）和铂（II）化合物具有金属-金属相互作用
2. Novel heterobimetallic compounds with metal-metal bonds: The use of quinolyl-substituted metallocenes as tridentate ligands [J] . Enders M., Kohl G., Pritzkow H. Organometallics . 2002,第6期

机译：具有金属-金属键的新型异双金属化合物：喹啉基取代的茂金属作为三齿配体的用途
3. New coordination compounds-of group IV metallocenes with framework alcoholato-ligands in homogeneous ethylene polymerization processes [J] . Grafov A.V. Украинский химический журнал . 1998,第10期

机译：均相乙烯聚合过程中IV类金属茂与骨架醇-配体的新配位化合物
4. Grubbs Catalysed ROMP to Synthesize Aryloxide Ligands containing Polynorbornene: Well-defined Polymer to Support Half-Metallocene Catalysts [C] . Ashutosh Thakur, Minoru Terano, Toshiaki Taniike 石油・石油化学討論会 . 2015

机译：Grubbs催化romp合成含有多冰片烯的芳氧化物配体：明确定义的聚合物以支持半茂金属催化剂
5. Ligand induced dinitrogen cleavage and functionalization by group four metallocenes [D] . Semproni, Scott Peter 2014

机译：配体诱导的四族茂金属对二氮的裂解和功能化
6. Similar ligand–metal bonding for transition metals and actinides? 5f1 U(C7H7)2–versus 3dn metallocenes [O] . Dumitru-Claudiu Sergentu, Frédéric Gendron, Jochen Autschbach 2002

机译：过渡金属和act系元素的类似配体-金属键合？ 5f1 U（C7H7）2-相对于3dn金属茂
7. Insight in Structures of Superbulky Metallocenes with the CpBIG Ligand: Theoretical Considerations of Decaphenyl Metallocenes [O] . Dennis Kuchenbecker, Sjoerd Harder, Georg Jansen 2010

机译：CPBIG配体的Superbulky Metallocenes结构的洞察：析寄生算子的理论考虑因素
8. Basicity of Coordinating Ligands in Trivalent Uranium and Cerium Metallocene Complexes [R] . Fabiano, M. D. 1988

机译：三价铀和铈茂金属配合物配位配合物的碱度

Half-open metallocenes with heterodienyl ligands and related compounds

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