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One-Pot Combination of Metal- and Bio-Catalysis in Water for the Synthesis of Chiral Molecules

机译：一锅法在水中进行金属和生物催化的合成，以合成手性分子

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During the last decade, the combination of different metal- and bio-catalyzed organic reactions in aqueous media has permitted the flourishing of a variety of one-pot asymmetric multi-catalytic reactions devoted to the construction of enantiopure and high added-value chemicals under mild reaction conditions (usually room temperature) and in the presence of air. Herein, a comprehensive account of the state-of-the-art in the development of catalytic networks by combining metallic and biological catalysts in aqueous media (the natural environment of enzymes) is presented. Among others, the combination of metal-catalyzed isomerizations, cycloadditions, hydrations, olefin metathesis, oxidations, C-C cross-coupling and hydrogenation reactions, with several biocatalyzed transformations of organic groups (enzymatic reduction, epoxidation, halogenation or ester hydrolysis), are discussed.
机译：在过去的十年中，水性介质中金属和生物催化的有机反应的结合使多种多样的一锅不对称多催化反应得以蓬勃发展，这些反应致力于在温和的条件下构建对映纯和高附加值化学品反应条件（通常为室温）和空气存在下。本文介绍了通过在水介质（酶的自然环境）中结合金属和生物催化剂，全面发展催化网络的最新方法。其中，讨论了金属催化的异构化，环加成，水合，烯烃复分解，氧化，C-C交叉偶联和氢化反应与有机基团的几种生物催化转化（酶还原，环氧化，卤化或酯水解）的组合。

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